Aluminium triethoxide
 | This article includes a list of general references, but it remains largely unverified because it lacks sufficient corresponding inline citations. (February 2012) |
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| Names | |
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| Other names
Aluminium ethoxide
Triethoxyaluminum | |
| Identifiers | |
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3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.008.279 
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PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties | |
| C6H15AlO3 | |
| Molar mass | 162.165 g·mol−1 |
| Appearance | White powder |
| Density | 1.142 g/cm3 |
| Melting point | 140 °C (284 °F; 413 K) |
| Boiling point | 320 °C (608 °F; 593 K) |
| reacts violently | |
| Solubility | slightly soluble in xylene, chlorobenzene |
| Hazards | |
| GHS pictograms |   [1]
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| GHS Signal word | Danger[1] |
GHS hazard statements
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H228, H314[1] |
| P210, P280, P305+351+338, P310[1] | |
| Flash point | 210 °C (410 °F; 483 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Aluminium triethoxide (also Aluminum ethoxide) is a reducing agent that exists as a white powder under room temperature and standard atmospheric pressure.[citation needed] The chemical is mainly used in industrial settings and has played an important role in reducing the cost of the production of bimetallic aluminium catalysts.[2]
Properties[]
Aluminium triethoxide is hygroscopic, and decomposes into aluminium hydroxide and ethanol after it absorbs moisture from the air. Aluminium triethoxide is slightly soluble in hot dimethyl benzene, chlorobenzene and other high boiling point non-polar solvents.[3]
Applications[]
Aluminium triethoxide is used as a reducing agent for aldehydes and ketones, and is also used as a polymerization catalyst. Aluminium triethoxide is mainly used in Sol-Gel Process preparation of high purity aluminium sesquioxide, which is a polymerization agent. At the same time, it is used as a reducing reagent, for example, carbonyl compounds that restore to alcohol.[clarification needed]
Synthesis methods[]
Aluminium triethoxide is produced by the heating reaction of an aluminium amalgam with anhydrous alcohol. All the reagents go through a strict water treatment, and the instrument devices prevent humidity from entering.
Alternatively, aluminium triethoxide is produced by reacting aluminium with anhydrous alcohol, with iodine (I
2) and mercuric chloride (HgCl
2) as catalysts.[4]
References[]
- ^ Jump up to: a b c d "Aluminum Ethoxide". American Elements. Retrieved 2019-07-15.
- ^ North, Michael; Young, Carl (2 November 2011). "Reducing the Cost of Production of Bimetallic Aluminium Catalysts for the Synthesis of Cyclic Carbonates". ChemSusChem. 4 (11): 1685–1693. doi:10.1002/cssc.201100239. PMID 22045591.
- ^ "Aluminium triethoxide". The Merck Index. Royal Society of Chemistry.
- ^ Wilhoit, R. C.; Burton, J. R.; Kuo, Fu-tien; Huang, Sui-Rong; Viquesnel, A. (1 December 1962). "Properties of aluminium ethoxide". Journal of Inorganic and Nuclear Chemistry. 24 (7): 851–861. doi:10.1016/0022-1902(62)80106-7. ISSN 0022-1902.
- Aluminium compounds
- Ethoxides