Bobbitt's salt

Bobbitt's salt
Names
	IUPAC name N-(2,2,6,6-tetramethyl-1-oxopiperidin-1-ium-4-yl)acetamide;tetrafluoroborate
	Other names 4-(Acetylamino)-2,2,6,6-tetramethyl-1-oxo-piperidinium tetrafluoroborate
Identifiers
CAS Number	219543-09-6;
3D model (JSmol)	Interactive image;
ChemSpider	2034373;
ECHA InfoCard	100.202.272
PubChem CID	2753331;
CompTox Dashboard (EPA)	DTXSID90372980 ;
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	show SMILES
Properties
Chemical formula	C11H21BF4N2O2
Molar mass	300.10 g·mol−1
Hazards
GHS pictograms
GHS Signal word	Warning
GHS hazard statements	H315, H319, H335
GHS precautionary statements	P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Bobbitt's salt is an oxoammonium compound derived from 4-acetamido-2,2,6,6-tetramethylpiperidine. It contains the tetrafluoroborate anion and is named after the American chemist James M. Bobbitt (born 1930).

As a less expensive analogue of the N-oxoammonium salt derived from TEMPO, Bobbitt's salt is still mainly used as a catalyst for oxoammonium-catalyzed oxidations.^[1]^[2]

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References[]

^ Nabyl Merbouh, James M. Bobbitt, Christian Brückner (2004). "Preparation of Tetramethylpiperdine-1-oxoammonlum Salts and Their Use as Oxidants in Organic Chemistry. A Review". Organic Preparations and Procedures International. 36: 1-31. doi:10.1080/00304940409355369.CS1 maint: uses authors parameter (link)
^ James M.Bobbitt, Nicholas A.Eddy, Jay J.Richardson, Stephanie A.Murray, Leon J.Tilley (2013). "Discussion Addendum for: Preparation of 4-Acetylamino-2, 2, 6, 6-tetramethylpiperidine-1-oxoammonium Tetrafluoroborate and the Oxidation of Geraniol to Geranial (2,6-Octadienal, 3,7-dimethyl-, (2e)-)". Org. Synth. 90: 215. doi:10.15227/orgsyn.090.0215.CS1 maint: multiple names: authors list (link)

[1] Nabyl Merbouh, James M. Bobbitt, Christian Brückner (2004). "Preparation of Tetramethylpiperdine-1-oxoammonlum Salts and Their Use as Oxidants in Organic Chemistry. A Review". Organic Preparations and Procedures International. 36: 1-31. doi:10.1080/00304940409355369.CS1 maint: uses authors parameter (link)

[2] James M.Bobbitt, Nicholas A.Eddy, Jay J.Richardson, Stephanie A.Murray, Leon J.Tilley (2013). "Discussion Addendum for: Preparation of 4-Acetylamino-2, 2, 6, 6-tetramethylpiperidine-1-oxoammonium Tetrafluoroborate and the Oxidation of Geraniol to Geranial (2,6-Octadienal, 3,7-dimethyl-, (2e)-)". Org. Synth. 90: 215. doi:10.15227/orgsyn.090.0215.CS1 maint: multiple names: authors list (link)

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