Group transfer reaction
![](http://upload.wikimedia.org/wikipedia/commons/thumb/7/76/Figure1newene.png/300px-Figure1newene.png)
The ene reaction
In organic chemistry, a group transfer reaction is a pericyclic process where one or more groups of atoms is transferred from one molecule to another. They can sometimes be difficult to identify when separate reactant molecules combine into a single product molecule (like in the ene reaction). Unlike other pericyclic reaction classes, group transfer reactions do not have a specific conversion of pi bonds into sigma bonds or vice versa, and tend to be less frequently encountered. Like all pericyclic reactions, they must obey the Woodward–Hoffmann rules.[1]
The best known group transfer reaction is the ene reaction in which an allylic hydrogen is transferred to an alkene.
References[]
- ^ J. Singh (2005). Photochemistry And Pericyclic Reactions. New Age International. pp. 135–139. ISBN 9788122416947.
Categories:
- Rearrangement reactions
- Pericyclic reactions
- Chemical reaction stubs