Moorhouseite

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Moorhouseite
General
CategorySulfate mineral
Formula
(repeating unit)
CoSO4•6H2O
IMA symbolMh[1]
Strunz classification7.CB.25
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupC2/c
Unit cella = 10.03, b = 7.23,
c = 24.26 [Å], β=98.37o (approximated); Z = 8
Identification
ColorPink
Crystal habitgranular; in crusts and efflorescences
FractureConchoidal
Mohs scale hardness2.5
LusterVitreous
StreakWhite
Density1.97-2.02 (measured)
Common impuritiesNi, Mn, Cu, Fe
References[2][3][4][5]

Moorhouseite is a rare mineral with the formula CoSO4•6H2O, a naturally occurring cobalt(II) sulfate hexahydrate. It is the lower-hydrate-equivalent of bieberite (heptahydrate) and aplowite (hexahydrate). It is also hydrated equivalent of . It occurs together with moorhouseite within efflorescences found in the Magnet Cove Barium Corporation mine in Walton, Nova Scotia, Canada.[6][7]

Notes on chemistry[]

Relatively high amounts of nickel and manganese were reported, with trace amounts of copper and iron.[8]

Crystal structure[]

Analysis of synthetic analogue of moorhouseite revealed, that its structure may be described as containing:[9]

  • Co(H2O)6 octahedra, forming alternate layers
  • SO4 tetrahedra
  • hydrogen bonds (two per a single water molecule)

References[]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85: 291–320.
  2. ^ Mineralienatlas
  3. ^ Jambor, J.L., and Boyle, R.W., 1984. Moorhouseite and aplowite, new cobalt minerals from Walton, Nova Scotia. Canadian Mineralogist 8, 166-171
  4. ^ "Moorhouseite" (PDF). Handbookofmineralogy.org. Retrieved 2016-03-10.
  5. ^ "Moorhouseite: Moorhouseite mineral information and data". Mindat.org. Retrieved 2016-03-03.
  6. ^ Jambor, J.L., and Boyle, R.W., 1984. Moorhouseite and aplowite, new cobalt minerals from Walton, Nova Scotia. Canadian Mineralogist 8, 166-171
  7. ^ "Moorhouseite: Moorhouseite mineral information and data". Mindat.org. Retrieved 2016-03-03.
  8. ^ Jambor, J.L., and Boyle, R.W., 1984. Moorhouseite and aplowite, new cobalt minerals from Walton, Nova Scotia. Canadian Mineralogist 8, 166-171
  9. ^ Elerman, Y., 1988. Refinement of the crystal structure of CoSO4.6H2O. Acta Crystallographica C44, 599-601


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