Nickel ternary chalcogenides
The Nickel ternary chalcogenides are a class of chemical compounds that contains nickel, a chalcogenide, and another element. Nickel forms a series of double nickel oxides with other elements, which may be termed "nickelates". These double nickel oxides are not listed on this page. There are also many well defined double compounds with sulfur, selenium and tellurium which are listed here.
formula | name | colour | structure | production | references |
---|---|---|---|---|---|
NH4NiS5 | ammonium nickel sulphide | black | NH4 polysulfide+NiSO4 | [1][2] | |
K2Ni3S4 | potassium nickel tetrasulfide | bronze yellow | Fddd a=10.023 b=26.074 c=5.704 | NiSO4 K2CO3 S | [1][3][4] |
K2Ni11S10 | potassium nickel decasulfide | dark metallic green | NiO+KCNS | [1] J. Milbauer | |
Na2Ni3S4 | sodium nickel tetrasulfide | dark yellow | NiSO4 Na2CO3 S | [1] R. Schneider | |
KNi2S2 | potassium dinickel disulfide | orange yellow | Ni foil, S, K at 723K | [5][6] | |
K2Ni3Se4 | potassium nickel tetraselenide | gold | Fddd a=10.468 b=26.496 c=5.995 | [7][8] | |
KNi2Se2 | potassium dinickel diselenide | purple-red | I4/mmmtetragonal a=3.909, c=13.4142 | Ni foil, Se shot, K at 723K | [5][9] |
CsNi2Se2 | caesium dinickel diselenide | tetragonal a=3.988, c=14.419 | heat elements | [10] | |
TlNi2Se2 | Thallium dinickel diselenide | gold metallic | tetragonal | heat elements together in closed quartz tube | [11] |
Rb2Ni3S4 | rubidium nickel tetrasulphide | metallic greenish gold | Fmmm orthorhombic a=9.901 Å, b=13.606 Å and c=5.861 Z=4 layered; ferromagnetic only after water immersion | [7][12] | |
Rb2Ni3Se4 | rubidium nickel tetraselenide | golden metallic | Fddd orthorhombic a = 10.555 Å, b = 27.588 Å, c = 6.031 Å, Z = 8 layered; ferromagnetic only after water immersion | Rb2CO3 S Ni | [13] |
Cs2Ni3S4 | cesium nickel tetrasulphide | greenish gold | Fmmm a=10.038 b=14.552 c=5.934 | [8][13] | |
Cs2Ni3S4 | cesium nickel tetrasulphide | gold | Fmmm a=10.540 b=14.624 c=6.194 | [8] | |
Cs0.9Ni3.1Se3 | Hexagonal P63/m a = 9.26301(4) Å and c = 4.34272(2) Å | quasi-one-dimensional electric conductor | [14] | ||
BaNi4S5 | Barium nickel pentasulfide | bronze yellow | NiSO4 K2CO3 S | [1] R. Schneider; I. and L. Bellucci | |
Pb2Ni3S2 | lead nickel disulfide | melt 790° | PbS Ni | [15] W Guertler; W Guertler H Schack | |
(Ni,Fe)9S8 | Pentlandite | bronze yellow melt 870 | [15] T. Scheerer | ||
Fe2Ni2S4 | ferrous nickel tetrasulfide | melt 840 | [16] K Bornemann | ||
Fe2Ni2S3 | ferrous nickel trisulfide | stable over 575°, melt 886, | [17] K Bornemann | ||
Fe3Ni4S5 | ferrous nickel pentasulfide | below 575 | [17] K Bornemann | ||
Fe4Ni2S5 | [17] K Bornemann | ||||
Fe2Ni3S4 | [17] K Bornemann | ||||
Fe3Ni4S5 | [17] K Bornemann | ||||
Fe2Ni2S3 | [17] K Bornemann | ||||
FeNi2S4 | Violarite | dark violet grey | mineral oxidate | ||
Ni3Sn2S2 | [18] | ||||
Ni3Bi2S2 | superconducting | [18] | |||
Ni3Bi2Se2 | superconducting | [18] | |||
NiSnS3 | nickel thiostannate | greenish black | orthorhombic a=6.88 b=7.89 c=11.95 Z=8 V=644 | NiCl2 + SnS2 | [19] |
NiGeS33 | nickelselenogermanate | [20] | |||
Ta2NiS5 | Orthorhombic | [21] | |||
Ta2NiSe5 | monoclinic β=90.53 | [21] | |||
Ta2Ni2Te4 | [22] | ||||
Ta2Ni3Te5 | [22] |
References[]
- ^ a b c d e Mellor p443
- ^ Ephraim, Fritz (17 September 1923). "Über Nickelsulfid". Berichte der Deutschen Chemischen Gesellschaft (A and B Series) (in German). 56 (8): 1885–1886. doi:10.1002/cber.19230560825.
- ^ Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie (in German). 375 (1): 1–7. doi:10.1002/zaac.19703750102.
- ^ Schneider, R. (1874). "Ueber neue Schwefelsalze". Annalen der Physik und Chemie. 227 (3): 437–450. Bibcode:1874AnP...227..437S. doi:10.1002/andp.18742270306.
- ^ a b Hlukhyy, Viktor; Trots, Dmytro; Fässler, Thomas F. (13 January 2017). "First-Order Phase Transition in BaNi2Ge2 and the Influence of the Valence Electron Count on Distortion of the Structure Type". Inorganic Chemistry. 56 (3): 1173–1185. doi:10.1021/acs.inorgchem.6b02190. PMID 28085271.
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- ^ a b Mellor p444
- ^ Mellor p445
- ^ a b c d e f Mellor p446
- ^ a b c Rommel, Stefan Michael; Krach, Alexander; Peter, Philipp; Weihrich, Richard (25 April 2016). "Conversion Reactions of Solids: From a Surprising Three-Step Mechanism towards Directed Product Formation". Chemistry. 22 (18): 6333–6339. doi:10.1002/chem.201505209. PMID 26997587.
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- ^ Popescu, M. A. (2001-11-30). Non-Crystalline Chalcogenicides. Springer Science & Business Media. p. 73. ISBN 9781402003592.
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- ^ a b Tremel, Wolfgang (July 1991). "Isolated and Condensed Ta2Ni2 Clusters in the Layered Tellurides and ". Angewandte Chemie International Edition in English. 30 (7): 840–843. doi:10.1002/anie.199108401.
Categories:
- Nickel compounds
- Chalcogenides