Sulfate fluoride

From Wikipedia, the free encyclopedia

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

Fluoride sulfates were first discovered by Jean Charles de Marignac in 1859.[1][2]

Some elements such as cobalt or uranium can form complexes that contain fluoride and sulfate groups, and would be referred to as fluoro and sulfato metallates.

List[]

Minerals[]

name formula ratio system space group unit cell Å volume density optical references
Ca4.5Al2(SO4)F13·12H2O 1:13 Isometric Fd3 a = 16.749 Z=8 4698.6 2.23 isotropic n = 1.432 [3]
Ca3(Y,Ce)(AlF6)2(SO4)F · 10H2O 1:13 Isometric Fd3 [4]
Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O 1:13 Isometric Fd3 [5]
Ca3(Nd,Y)Al2(SO4)F13·12H2O 1:13 Isometric Fd3 a = 16.759 Z=8 4,707.0 2.42 isotropic nα = 1.443 [6]
Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O 1:13 Isometric Fd3 a = 16.722 Z=8 4,675.89 Isotropic n = 1.43
Pb6(SO4)F10 1:10 Orthorhombic F2 2 2 a = 8.51 b = 19.57 c = 8.49 Z=4 1,413.93 Biaxial (+) nα = 1.864 nβ = 1.865 nγ = 1.873

2V: measured: 30° , calculated: 40°

Max birefringence: δ = 0.009

[7]
Creedite Ca3SO4Al2F8(OH)2 · 2H2O 1:8 Monoclinic B2/b a = 13.936, b = 8.606, c = 9.985 β = 94.39° Z=4 1,194.02 2.713 Biaxial (-) nα = 1.461 nβ = 1.478 nγ = 1.485

Max birefringence: δ = 0.024

[8]
K2AlF3(SO4) 1:3 Orthorhombic Pbcn a = 10.81 b = 8.336 c = 6.822 614.75 2.77
Grandreefite Pb2(SO4)F2 1:2 monoclinic A2/a a = 8.667 b = 4.4419 c = 14.242 β = 107.418 Z=4 523.15 7.15 Biaxial (+) nα = 1.872 nβ = 1.873 nγ = 1.897

2V: Measured: 23°

Max Birefringence: δ = 0.025

[9]
Al2F(PO4)(SO4) · 9H2O 1:1 monoclinic P2/a a = 7.073 b = 9.634 c = 10.827 β = 100.40 Z = 2 725.7 2.01 Biaxial (+) ?nα = 1.493(5) nγ = 1.485(5)

Max birefringence: δ = 0.008

[10][11]
Al(SO4)F · 5H2O 1:1 orthorhombic a = 11.17 b = 13.05 c = 10.88 1,585.96 1.925 Biaxial (-) nα = 1.440 nβ = 1.460 nγ = 1.487

2V: measured: 68° calculated: 84°

Max birefringence δ = 0.047

colourless

[12]
Kogarkoite Na3(SO4)F 1:1 Monoclinic ?P21 a = 18.07 b = 6.94 c = 11.44 β = 107.72° Z=12 1,366.58 2.676 Biaxial (+) nα = 1.439 nβ = 1.439 nγ = 1.442

Max Birefringence: δ = 0.003

[13]
NaMg(SO4)F 1:1 monoclinic C2/c a = 6.662 b = 8.584 c = 7.035 β = 114.06 Z=4 367.4 2.91 biaxial (+), nα = 1.488 nβ = 1.491 nγ = 1.496 2Vmeas = 75°

Max birefringence: δ = 0.008

[14]
Mg2Ca4Al4(SO4)8F8 · 24H2O 8:8 Tetragonal I4/m a = 6.860 c = 28.053 1,320.16 2.22 Uniaxial (+) nω = 1.460 nε = 1.478

Max Birefringence:δ = 0.018

[15]
Na6(SO4)2FCl 2:1 Isometric Fm3m Isotropic [16]
Uklonskovite NaMgSO4F•2H2O 1:1 monoclinic a = 7.2 Å, b = 7.21 Å, c = 5.73 β = 113.23° 273.34 Biaxial (+) nα = 1.476 nγ = 1.500

Max Birefringence δ = 0.024

[17]
AlCa2(SO4)2F2Cl · 4H2O 2:2 Tetragonal I4/m a = 6.870, c = 13.342 Z=2 629.70 Uniaxial (+) nω = 1.509 nε = 1.526

Max birefringence: δ = 0.017

[18]
Na21(SO4)7ClF6 7:6 trigonal 3_2/m a = 12.17 c = 19.29 2,474.25 2.67 Uniaxial (+) nω = 1.440 nε = 1.445

Max birefringence: δ = 0.005

[19]
Na15(SO4)5F4Cl 5:4 Trigonal a = 12.17 c = 13.94 1,788.03 Uniaxial (+) nω = 1.447 nε = 1.449

Max Birefringence: δ = 0.002

[20]
Fluorellestadite Ca10(SiO4)3(SO4)3F2 3:2 hexagonal a = 9.53 c = 6.91 543.49 3.03 Uniaxial (-) nω = 1.655 nε = 1.650

Max birefringence:δ = 0.005

[21]
Al(UO2)(SO4)2F·16H2O 2:1 monoclinic C2/c a = 11.0187 b = 8.3284 c = 26.673 β = 97.426° 2427.2 2.20 pale yellowish green

Biaxial (-) nα = 1.477(2) nβ = 1.485(2) nγ = 1.489(2)

2V: measured: 70° calculated: 70.2°

Max birefringence: δ = 0.012

[22]
(Mg,Mn2+,Ca)(Al,Fe3+)(SO4)2F · 14H2O 2:1 triclinic a = 6.21 b = 13.3 c = 6.25 α = 90.15°, β = 93.56°, γ = 82.08° 510.29 Biaxial (-) nα = 1.423 nβ = 1.439 nγ = 1.444

2V: calculated: 56°

Max birefringence: δ = 0.021

[23]
MgAl(SO4)2F · 17H2O 2:1 triclinic P1 a = 6.644, b = 6.749, c = 14.892 α = 79.664°, β = 80.113°, γ = 62.487 579.6 1.58 Biaxial (-) nα = 1.424 nβ = 1.436 nγ = 1.438

2V: measured: 48° , calculated: 44°

Max birefringence: δ = 0.014

[24]
KNa2CaMg(SO4)3F 3:1 hexagonal P63/mcm a = 16.6682 c = 6.9007 Z = 6 1660.36 2.68 Uniaxial (-) nω = 1.500 nε = 1.492

Max birefringence: δ = 0.008

[25]
K2(Ca2Na)(SO4)3F 3:1 orthorhombic Pnma a = 13.2383 b = 10.3023 c = 8.9909 Z = 4 1226.22 2.64 biaxial (−), nα = 1.493 nβ = 1.498 nγ = 1.498 2Vmeasured ≤ 20 [26]

Artificial[]

name formula MW ratio system space group unit cell volume density optical CAS references
LiMgFSO4 1:1 triclinic P1 a = 5.1623 b = 5.388 c = 7.073 α = 106.68 β=107.40 and γ=97.50° Z=2 [27]
NaMgSO4F 1:1 monoclinic C2/c Z=4 109.802 2.84 [28]
Na4TiF4(SO4)2 2:4 [29]
β-K3[SO4]F 1:1 tetragonal I4/mcm a= 7.2961 c= 10.854 [30]
α-K3[SO4]F 1:1 cubic Pm3m a≈5.43 ≥585 °C [30]
KMgSO4F 1:1 [31]
sodium calcium sulfapatite Na6Ca4(SO4)6F2 6:2
K3Ca2(SO4)3F 3:1 orthorhombic Pn21a a=13.467 b=10.521 c=9.167 Z=4 1299.9 [32]
[N2C10H12] TiF4SO4 378.16? 1:4 triclinic P1 a=8.691 b=9.208 c=9.288 α=68.56 β=84.30 γ=81.59 Z=2               683.6 1.837 colourless [29]
[N2C10H12]TiF2(SO4)2 436.22? 2:2 triclinic P1 a=4.5768 b=8.9162 c=10.1236 α=112.888 β=95.196 γ=98.706 Z=1               371.11 1.952 colourless [29]
Rb2TiF2(SO4)2 · 2H2O, [33]
Cs2TiF2(SO4)2 · 3H2O [33]
[N2C6H16]V(SO4)2F 378.27 2:1 monoclinic P21/c a=10.262 b =17.761 c=7.0518 β=93.93 Z=4                  1282.3 1.959 green [29]
Na2VF3SO4 1:3 [29]
Na3CrF2(SO4)2 2:2 [29]
LiMnSO4F 1:1 monoclinic a=13.2406 b=6.4082 c=10.0229 β=120.499 732.76 [34]
[N2C6H16]2+Mn2F2(SO4)2 2:2 [29]
Li2MnF3(SO4) 1:3 pink-brown [35]
(NH4)2MnF3(SO4) 1:3 pink-brown [35]
Na2MnF3(SO4) 1:3 pink-brown [35]
Dipotassium trifluorosulfato manganate(III) K2MnF3(SO4) 1:3 pink-brown [35]
FeFSO4 170.91 1:1 monoclinic C2/c a = 7.3037 b = 7.0753 c = 7.3117 β = 119.758° 328.017 3.461 [36]
K2FeF3SO4 1:3 [29]
Li3FeF2(SO4)2·H2O 2:2 [29]
[N2C6H16]Fe(SO4)2F 383.18 2:1 monoclinic P21/c a=10.2220 b=17.6599 c=7.0437 β=93.894 Z=4 1268.59 2.006 brown [29]
LiFeFSO4 177.85 1:1 triclinic P1 a = 5.1751 b = 5.4915 c = 7.2211 α = 106.506° β = 107.178° γ=97.865° 182.44 3.237 grass green [36]
sodium ferrous sulfate fluoride NaFeFSO4 193.91 1:1 monoclinic P21/c a = 6.6739 b = 8.6989 c = 7.1869 β = 113.525° 382.567 3.366 [36]
sodium ferrous sulfate fluoride dihydrate NaFeFSO4·2H2O 1:1 monoclinic P21/m a=5.75959 b=7.38273 c=7.25047 β=113.3225 283.109 white [37]
trisodium ferric disulfate difluoride Na3Fe(SO4)2F2 2:2 orthorhombic Pnca a = 6.6419 b = 8.8115 c = 14.0023 [38]
NaCoFSO4 1:1 monoclinic C2/c a=6.6687 b=8.6251 c=7.1444 β=114.323 374.46 [39]
NaCoFSO4·2H2O 1:1 monoclinic P21/m a=5.73364 b=7.31498 c=7.18640 β=113.5028 276.40 pink [37]
NH4CoFSO4·2H2O 1:1 [40]
KCoFSO4·2H2O 1:1 [40]
NaNiFSO4·2H2O 1:1 monoclinic P21/m a=5.70118 b=7.27603 c=7.15634 β=113.8883 271.429 green [37]
LiZnSO4F 1:1 orthorhombic Pnma 7.40357 b=6.32995 c=7.42016 347.740 [41]
K2Zn3(SO4)(HSO4)2F4 orthorhombic Cmc21 a=17.725 b=7.6650 c=9.7505 Z=4 1324.7 3.212 colourless [42]
Y(SO4)F 203.97 1:1 orthorhombic Pnma a=8.3128, b=6.9255, c=6.3905 Z=4 367.90 3.682 [43]
Y2Cu(OH)3(SO4)2F·H2O 521.52 2:1 monoclinic P21/n a=11.6889, b=6.8660, c=12.5280, β=97.092° Z=4 997.8 3.472 blue [43]
Zr2O2F2SO4 · 6H2O 1:2 [44]
α-K3ZrF5SO4 · H2O 1:5 [33]
K2ZrF4SO4 1:4 [33]
K2ZrF2(SO4)2 · 2.5H2O 2:2 [33]
K3Zr2F9SO4 · 2H2O 1:9 [33]
(NH4)3Zr2F9SO4 · 2H2O 1:9 [33]
(NH4)2ZrF4SO4 1:4 [33]
(NH4)2ZrF2(SO4)2 · 2.5H2O 2:2 [33]
Rb2ZrF4SO4 1:4 [33]
Rb2ZrF2(SO4)2 · 3H2O 2:2 [33]
Rb3Zr2F9SO4 ·2H2O 1:9 [33]
RbZr2O2F(SO4)2 · 5H2O 2:1 [33]
Cs2ZrF4SO4 1:4 [33]
Cs2ZrF2(SO4)2 · 2H2O 2:2 [33]
Cs8Zr4F2(SO4)11 · 16H2O 11:2 [33]
CsZr2O2F(SO4)2 · 6H2O 2:1 [33]
Zr2O2F2SO4 · 5H2O 1:2 [33]
triindium trifluoride sulfate ditellurite hydrate In3(SO4)(TeO3)2F3(H2O) 866.74 1:3 orthorhombic P212121 a=8.3115 b=9.4341 c=14.8068 1161.0 4.959 band gap 4.10 eV; white [45]
4,4'-bipyridine distannous difluoride disulfate (C10H10N2)0.5[SnF(SO4)] 2:2 triclinic P1 a=4.726 b=7.935 c=11.203 α = 81.05° β = 87.59° γ=73.70° Z=2 398.3 2.608 colourless [46]
diantimony dipotassium hexafluoride sulfate K2SO4·(SbF3)2 531.76 1:6 monoclinic P21/c a=9.1962 b=5.6523 c=19.2354 β =103.209 Z=4 973.40 3.629 colourless [47]
diantimony dirubidium hexafluoride sulfate Rb2SO4·(SbF3)2 624.50 1:6 monoclinic P21 a=9.405 b=5.7210 c=9.879 β = 103.850 Z=2 516.1 4.018 colourless [47]
tetraantimony hexarubidium dodecafluoride trisulfate Rb6Sb4F12(SO4)3 1515.989 3:12 trigonal P3 a=16.9490 c=7.5405 Z=2 1875.94 4.026 white 53168-89-1 [48][49]
hexaammonium dodecafluorotrisulfatotetraantimonate(III) [NH4]6Sb4F12(SO4)3 3:12 trigonal P3 a=17.07 c=7.515 Z=3 1896 2.92 [50]
hexarubidium dodecafluorotrisulfatotetraantimonate(III) Rb6Sb4F12(SO4)3 3:12 [50]
tetraantimony hexacaesium dodecafluoride trisulfate Cs6Sb4F12(SO4)3 1800.601 3:12 triclinic P1 a=7.9044 b=10.5139 c=17.3534 al=90.350 β = 90.151 ga=104.797 Z=4 1394.3 4.289 white 53200-54-7 [48][51]
antimony caesium difluoride sulfate CsSbF2SO4 388.72 1:2 orthorhombic Pna21 a=9.9759 b=11.6616 c=5.2968 515.20 4.19 clear, non-linear SH [52]
LiLa2F3(SO4)2 2:3 monoclinic I2/a a = 8.283, b = 6.947, c = 14.209 β = 95.30° Z=4 [53]
NdFSO4·H2O 277.32 1:1 monoclinic P21/n a = 4.9948 b = 7.3684 c = 11.6366 β = 96.672° Z=4 425.37 4.330 pink [54]
NaPr2F3(SO4)2 2:3 monoclinic I2/a a = 8.223, b = 6.9212, c = 14.199, β = 95.88° Z=4 light green [55]
LiEr2F3(SO4)2 2:3 orthorhombic Pbcn a = 14.791, b = 6.336, c = 8.137 [53]
hexa(triethylenetriammonium) tetrasamarium tetradecasulfate difluoride [C4H16N3]6[Sm4F2(SO4)14] 2621.43 14:2 triclinic P1 a = 11.1988 b = 11.4073 c = 16.2666 α = 89.901°, β = 82.406°, γ = 67.757° Z=1 1903.9 2.286 colourless [54]
TbFSO4·H2O 292.00 1:1 monoclinic P21/n a = 5.0014 b = 7.377 c = 11.651 β = 96.692° Z=4 426.9 4.543 colourless [54]
gadolinium fluoride sulfate GdF[SO4] 1:1 orthorhombic Pnma a=8.436 b=7.0176 c=6.4338 Z=4 [56]
γ-K2HfF2(SO4)2 · 2H2O 2:2 [33]
K2HfF2(SO4)2 · 2.5H2O 2:2 [33]
Na6Pb4(SO4)6F2 6:2 [57]
ThSO4F2.H2O 1:2 monoclinic P21n a = 6.9065 b = 6.9256 c = 10.589 β = 96.755° Z = 4 502.98 colourless [58]
potassium catena-di—fluoro-difluorotetraoxo-di—sulphato-diuranate(VI) hydrate K2UF2O2(SO4)·H2O 1:2 monoclinic P21/c a = 9.263 b = 8.672 c = 11.019 β= 101.60° Z = 4 867.1 3.83 greenish yellow [59][60]
(NH4)2[UO2F2(SO4)] triclinic P1 a=9.73 b=10.28 c=11.37 α = 107.4°, β = 111.9°, γ =106.9 Z=2 greenish yellow [60]
(NH4)6[(UO2)2F4(SO4)3] triclinic P1 a=9.35 b=9.85 c=11.25 α = 109.2°, β = 113.1°, γ =102.5 Z=1 greenish yellow [60]
Cs2[(UO2)2F4(SO4)] greenish yellow [60]
(NH4)[UO2F(SO4)] triclinic P1 a=8.99 b=7.12 c=7.42 α = 114.5°, β = 117.4°, γ =103.2 Z=1 1.92 greenish yellow [60]
RbUO2SO4F orthorhombic Pca21 a=25.353 b=6.735 c=11.496 Z=12 [61][62]
[N2C6H16][UO2F2(SO4)] 520.29 1:2 triclinic P1 a=6.9105 b=9.6605 =10.1033 α=72.6594(14) β=87.068 γ=77.9568 Z=2 629.62 2.744 yellow [63]
[N2C6H16][UO2F(SO4)]2 884.37 2:2 orthorhombic Pmmn a=6.9503 b=17.2147 c=7.0867 Z=2 847.90 3.464 yellow [63]
[N2C3H12][UO2F(SO4)]2·H2O 862.32 2:2 orthorhombic Pnma a=13.5775 b=14.6180 c=8.1168 Z=4 1610.99 3.555 yellow [63]
[N2C5H14][UO2F(H2O)(SO4)]2 907.38 2:2 monoclinic P121/n1 a=8.4354 b=15.5581 c=14.8442 β =96.666 Z=4 1935.0 3.115 yellow [63]
[N2C6H18]2[UO2F(SO4)]4·H2O 1792.80 4:4 triclinic P1 a=10.8832 b=10.9386 c=16.5325 ��=75.6604 β=73.6101 γ=89.7726 Z=2 1824.73 3.263 yellow [63]
[N2C3H12][UO2F(SO4)]2·H2O 864.34 2:2 monoclinic P121/n1 a=6.7745 b=8.1589 c=14.3661 β =94.556 Z=2 791.54 3.626 yellow [63]
diammonium hydrazinium triuranium(IV) tetrafluoride hexasulfate U4+3F4(SO4)6·2NH4·H3N-NH3 1436.6 6:4 monoclinic C2/c a=15.2309 b=8.77998 c=18.8590 β=105.5030 Z=4 2432.69 4.392 green [64]

References[]

  1. ^ Avdontceva, Margarita S.; Zolotarev, Andrey A.; Krivovichev, Sergey V. (November 2015). "Order–disorder phase transition in the antiperovskite-type structure of synthetic kogarkoite, Na3SO4F". Journal of Solid State Chemistry. 231: 42–46. Bibcode:2015JSSCh.231...42A. doi:10.1016/j.jssc.2015.07.033.
  2. ^ de Marignac, Jean Charles (1859). Recherches sur les formes cristallines et la composition chimique de divers sels. Annales des mines. p. 221.
  3. ^ "Chukhrovite-(Ca): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  4. ^ "Chukhrovite-(Ce): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  5. ^ "Chukhrovite-(Y): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  6. ^ "Chukhrovite-(Nd): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  7. ^ "Pseudograndreefite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  8. ^ "Creedite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  9. ^ "Grandreefite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  10. ^ Yakubovich, O. V.; Steele, I. M.; Chernyshev, V. V.; Zayakina, N. V.; Gamyanin, G. N.; Karimova, O. V. (August 2014). "The crystal structure of arangasite, Al 2 F(PO 4 )(SO 4 )·9H 2 O determined using low-temperature synchrotron data". Mineralogical Magazine. 78 (4): 889–903. Bibcode:2014MinM...78..889Y. doi:10.1180/minmag.2014.078.4.09. ISSN 0026-461X. S2CID 94078023.
  11. ^ "Arangasite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  12. ^ "Khademite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  13. ^ "Kogarkoite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  14. ^ Pekov, Igor V.; Krzhizhanovskaya, Maria G.; Yapaskurt, Vasiliy O.; Belakovskiy, Dmitry I.; Chukanov, Nikita V.; Lykova, Inna S.; Sidorov, Evgeny G. (2015-07-27). "Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia". European Journal of Mineralogy. 27 (4): 575–580. Bibcode:2015EJMin..27..575P. doi:10.1127/ejm/2015/0027-2457. ISSN 0935-1221.
  15. ^ "Lannonite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  16. ^ "Sulphohalite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  17. ^ "Uklonskovite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  18. ^ "Vlodavetsite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  19. ^ "Schairerite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  20. ^ "Galeite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  21. ^ "Fluorellestadite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  22. ^ "Straßmannite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  23. ^ "Svyazhinite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  24. ^ "Wilcoxite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  25. ^ Pekov, I. V.; Zelenski, M. E.; Zubkova, N. V.; Ksenofontov, D. A.; Kabalov, Y. K.; Chukanov, N. V.; Yapaskurt, V. O.; Zadov, A. E.; Pushcharovsky, D. Y. (2012-10-01). "Krasheninnikovite, KNa2CaMg(SO4)3F, a new mineral from the Tolbachik volcano, Kamchatka, Russia". American Mineralogist. 97 (10): 1788–1795. Bibcode:2012AmMin..97.1788P. doi:10.2138/am.2012.4104. ISSN 0003-004X. S2CID 98050549.
  26. ^ Pekov, Igor V.; Zubkova, Natalia V.; Britvin, Sergey N.; Chukanov, Nikita V.; Yapaskurt, Vasiliy O.; Sidorov, Evgeny G.; Pushcharovsky, Dmitry Y. (2016-03-23). "Shuvalovite, K2(Ca2Na)(SO4)3F, a new mineral from the Tolbachik volcano, Kamchatka, Russia". European Journal of Mineralogy. 28 (1): 53–62. Bibcode:2016EJMin..28...53P. doi:10.1127/ejm/2015/0027-2471. ISSN 0935-1221.
  27. ^ Sebastian, Litty; Gopalakrishnan, Jagannatha; Piffard, Yves (2002-01-24). "Synthesis, crystal structure and lithium ion conductivity of LiMgFSO4". Journal of Materials Chemistry. 12 (2): 374–377. doi:10.1039/b108289m.
  28. ^ Persson, Kristin (2016), Materials Data on NaMgSO4F (SG:15) by Materials Project, LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States), doi:10.17188/1310136, retrieved 2020-06-15
  29. ^ a b c d e f g h i j Marshall, Kayleigh L.; Wang, Qianlong; Sullivan, Hannah S. I.; Weller, Mark T. (2016). "Synthesis and structural characterisation of transition metal fluoride sulfates". Dalton Transactions. 45 (21): 8854–8861. doi:10.1039/C6DT00582A. ISSN 1477-9226. PMID 27151299.
  30. ^ a b Skakle, Janet M. S.; Fletcher, James G.; West, Anthony R. (1996). "Polymorphism, structures and phase transformation of K3[SO4]F". Journal of the Chemical Society, Dalton Transactions (12): 2497. doi:10.1039/dt9960002497. ISSN 0300-9246.
  31. ^ Poddar, Anuradha; Gedam, S.C.; Dhoble, S.J. (November 2013). "Photoluminescence study of KMgSO4F:X (X=Cu+ or Dy3+ or Eu3+) halosulfate phosphor". Journal of Luminescence. 143: 579–582. Bibcode:2013JLum..143..579P. doi:10.1016/j.jlumin.2013.06.010.
  32. ^ Triviño Vázquez, F. (July 1985). "A new compound: K3Ca2 (SO4)3F, identified in coatings of heat recover cyclones". Cement and Concrete Research. 15 (4): 581–584. doi:10.1016/0008-8846(85)90055-9.
  33. ^ a b c d e f g h i j k l m n o p q r s t Boroznovskaya, N. N.; Godneva, M. M.; Motov, D. L.; Klimkin, V. M. (April 2007). "Synthesis and luminescent properties of alkali-metal and ammonium fluorosulfatozirconates and fluorosulfatohafnates". Inorganic Materials. 43 (4): 425–429. doi:10.1134/S0020168507040176. ISSN 0020-1685. S2CID 97061342.
  34. ^ Tripathi, Rajesh; Popov, Guerman; Ellis, Brian L.; Huq, Ashfia; Nazar, L. F. (2012). "Lithium metal fluorosulfate polymorphs as positive electrodes for Li-ion batteries: synthetic strategies and effect of cation ordering". Energy & Environmental Science. 5 (3): 6238. doi:10.1039/c2ee03222h. ISSN 1754-5692.
  35. ^ a b c d Bhattacharjee, M.N.; Chaudhuri, M.K. (January 1984). "Alkali-metal trifluoromonosulphatomanganates (III) A2[MnF3(SO4)] (A = NH4, Li, Na or K)". Polyhedron. 3 (5): 599–602. doi:10.1016/S0277-5387(00)88094-8.
  36. ^ a b c Tripathi, Rajesh; Ramesh, T. N.; Ellis, Brian L.; Nazar, Linda F. (2010-11-08). "Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials". Angewandte Chemie International Edition. 49 (46): 8738–8742. doi:10.1002/anie.201003743. PMID 20941717.
  37. ^ a b c Ati, M.; Dupont, L.; Recham, N.; Chotard, J.N.; Walker, W.T.; Davoisne, C.; Barpanda, P.; Sarou-Kanian, V.; Armand, M.; Tarascon, J.M. (2010-07-13). "Synthesis, Structural, and Transport Properties of Novel Bihydrated Fluorosulphates NaMSO 4 F·2H 2 O (M = Fe, Co, and Ni)". Chemistry of Materials. 22 (13): 4062–4068. doi:10.1021/cm1010482. ISSN 0897-4756.
  38. ^ Long, Zhao; Wei, Liu; Shuang, Liu; lixin, Cao; Ge, Su; Rongjie, Gao (November 2015). "The first anhydrous metal fluorosulfate Na3Fe(SO4)2F2 with layered structure prepared via the interesting "tailor" role of fluorine ions based on Na3Fe(SO4)2". Inorganica Chimica Acta. 438: 191–195. doi:10.1016/j.ica.2015.09.020.
  39. ^ Melot, B. C.; Rousse, G.; Chotard, J.-N.; Kemei, M. C.; Rodríguez-Carvajal, J.; Tarascon, J.-M. (2012-03-12). "Magnetic structure and properties of NaFeSO 4 F and NaCoSO 4 F". Physical Review B. 85 (9): 094415. Bibcode:2012PhRvB..85i4415M. doi:10.1103/PhysRevB.85.094415. ISSN 1098-0121.
  40. ^ a b Bhattacharjee, Manabendra N.; Chaudhuri, Mihir K.; Devi, Meenakshi; Yhome, Khriesavilie (1987). "Direct synthesis of alkali trifluorocobaltate( II ) monohydrates, A[CoF 3 ]·H 2 O (A = NH 4 , Na, or K). First synthesis and structural assessment of mixed-ligand fluoro complexes of cobalt( II ), [Co(NH 3 ) 4 F 2 ] and A[CoF(SO 4 )(H 2 O) 2 ](A = NH 4 , Na, or K)". J. Chem. Soc., Dalton Trans. (5): 1055–1057. doi:10.1039/DT9870001055. ISSN 0300-9246.
  41. ^ Barpanda, Prabeer; Chotard, Jean-Noël; Delacourt, Charles; Reynaud, Marine; Filinchuk, Yaroslav; Armand, Michel; Deschamps, Michael; Tarascon, Jean-Marie (2011-03-07). "LiZnSO4F Made in an Ionic Liquid: A Ceramic Electrolyte Composite for Solid-State Lithium Batteries". Angewandte Chemie International Edition. 50 (11): 2526–2531. doi:10.1002/anie.201006331. PMID 21370330.
  42. ^ Zhou, Yang; Zhang, Xingyu; Xiong, Zheyao; Long, Xifa; Li, Yanqiang; Chen, Yangxin; Chen, Xin; Zhao, Sangen; Lin, Zheshuai; Luo, Junhua (2021-08-23). "Non-π-Conjugated Deep-Ultraviolet Nonlinear Optical Crystal K 2 Zn 3 (SO 4 )(HSO 4 ) 2 F 4". The Journal of Physical Chemistry Letters: 8280–8284. doi:10.1021/acs.jpclett.1c01533. ISSN 1948-7185.
  43. ^ a b Wang, Xiqu; Liu, Lumei; Ross, Kent; Jacobson, Allan J. (January 2000). "Synthesis and crystal structures of yttrium sulfates Y(OH)(SO4), Y(SO4)F, YNi(OH)3(SO4)-II and Y2Cu(OH)3(SO4)2F·H2O". Solid State Sciences. 2 (1): 109–118. doi:10.1016/S1293-2558(00)00107-2.
  44. ^ Godneva, M. M.; Motov, D. L.; Kuznetsov, V. Ya (2002). "Phase formation in the ZrO2 – H2SO4 – LiF(HF) – H2O system". Zhurnal Neorganicheskoj Khimii (in Russian). 47 (2): 312–318. ISSN 0044-457X.
  45. ^ Gong, Ya-Ping; Ma, Yun-Xiang; Ying, Shao-Ming; Mao, Jiang-Gao; Kong, Fang (2019-08-19). "Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)". Inorganic Chemistry. 58 (16): 11155–11163. doi:10.1021/acs.inorgchem.9b01730. ISSN 0020-1669. PMID 31365247.
  46. ^ Detkov, D. G.; Gorbunova, Yu. E.; Kazarinova, A. S.; Mikhailov, Yu. N.; Kokunov, Yu. V. (2003). "Polymeric Tin(II) Complexes with Dibasic Nitrogen-Containing Organic Cations. Synthesis and Crystal Structure of (C10H10N2)0.5[SnF(SO4]". Russian Journal of Coordination Chemistry. 29 (7): 451–454. doi:10.1023/A:1024721310366. S2CID 92085359.
  47. ^ a b Wang, Qian; Wang, Lei; Zhao, Xiaoyu; Huang, Ling; Gao, Daojiang; Bi, Jian; Wang, Xin; Zou, Guohong (2019). "Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size". Inorganic Chemistry Frontiers. 6 (11): 3125–3132. doi:10.1039/C9QI01036J. ISSN 2052-1553.
  48. ^ a b Dong, Xuehua; Long, Ying; Zhao, Xiaoyu; Huang, Ling; Zeng, Hongmei; Lin, Zhien; Wang, Xin; Zou, Guohong (22 May 2020). "A6Sb4F12(SO4)3 (A = Rb, Cs): Two Novel Antimony Fluoride Sulfates with Unique Crown-like Clusters". Inorganic Chemistry. 59 (12): 8345–8352. doi:10.1021/acs.inorgchem.0c00756. PMID 32441103.
  49. ^ "Landolt-Börnstein Substance / Property Index". lb.chemie.uni-hamburg.de. Retrieved 2020-05-25.
  50. ^ a b Waśkowska, A.; Lis, T. (1988-08-15). "Structure of hexaammonium dodecafluorotrisulfatotetraantimonate(III) at 300 K". Acta Crystallographica Section C Crystal Structure Communications. 44 (8): 1342–1345. doi:10.1107/S0108270188003774.
  51. ^ "Landolt-Börnstein Online Search". lb.chemie.uni-hamburg.de. Retrieved 2020-05-25.
  52. ^ Dong, Xuehua; Huang, Ling; Hu, Cuifang; Zeng, Hongmei; Lin, Zhien; Wang, Xin; Ok, Kang Min; Zou, Guohong (2019-05-13). "CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure". Angewandte Chemie International Edition. 58 (20): 6528–6534. doi:10.1002/anie.201900637. ISSN 1433-7851. PMID 30805990.
  53. ^ a b Wickleder, Mathias S. (1999). "LiLa2F3(SO4)2 und LiEr2F3(SO4)2: Fluoridsulfate der Selten-Erd-Elemente mit Lithium". Zeitschrift für anorganische und allgemeine Chemie (in German). 625 (2): 302–308. doi:10.1002/(SICI)1521-3749(199902)625:2<302::AID-ZAAC302>3.0.CO;2-Y. ISSN 1521-3749.
  54. ^ a b c Zhou, Wanli; Xu, Yan; Han, Lijie; Zhu, Dunru (2010). "Solvothermal syntheses, crystal structures and luminescence properties of three new lanthanide sulfate fluorides". Dalton Transactions. 39 (15): 3681–6. doi:10.1039/b926131a. ISSN 1477-9226. PMID 20354621.
  55. ^ Wickleder, Mathias S. (2000). "Synthese und Kristallstruktur von NaPr2F3(SO4)2". Zeitschrift für anorganische und allgemeine Chemie. 626 (8): 1723–1724. doi:10.1002/1521-3749(200008)626:8<1723::AID-ZAAC1723>3.0.CO;2-1. ISSN 1521-3749.
  56. ^ Wickleder, Mathias S. (1999). "Halogenidsulfate des Gadoliniums: Synthese und Kristallstruktur von GdClSO4 und GdFSO4". Zeitschrift für anorganische und allgemeine Chemie (in German). 625 (5): 725–728. doi:10.1002/(SICI)1521-3749(199905)625:5<725::AID-ZAAC725>3.0.CO;2-T. ISSN 1521-3749.
  57. ^ Ptáček, Petr (2016-04-13). Apatites and their Synthetic Analogues: Synthesis, Structure, Properties and Applications. BoD – Books on Demand. p. 227. ISBN 978-953-51-2265-4.
  58. ^ Zhao, Yanyan; Wang, Chunxiang; Su, Jing; Wang, Yaxing; Wang, Yanlong; Wang, Shuao; Diwu, Juan; Liu, Zhihong (October 2015). "Insights into the new Th (IV) sulfate fluoride complex: Synthesis, crystal structures, and temperature dependent spectroscopic properties". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 149: 295–303. doi:10.1016/j.saa.2015.04.037. PMID 25965512.
  59. ^ Alcock, N. W.; Roberts, M. M.; Chakravorti, M. C. (1980-03-01). "Structure of potassium catena -di-μ-fluoro-difluorotetraoxo-di-μ-sulphato-diuranate(VI) hydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 36 (3): 687–690. doi:10.1107/S0567740880004141. ISSN 0567-7408.
  60. ^ a b c d e Chakravorti, M.C.; Bharadwaj, P.K. (January 1979). "Fluoro complexes of hexavalent uranium—VII". Journal of Inorganic and Nuclear Chemistry. 41 (8): 1149–1152. doi:10.1016/0022-1902(79)80474-1.
  61. ^ Lussier, Aaron J.; Lopez, Rachel A.K.; Burns, Peter C. (January 2016). "A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds". The Canadian Mineralogist. 54 (1): 177–283. doi:10.3749/canmin.1500078. ISSN 0008-4476.
  62. ^ Mikhailov, Yu. N.; Gorbunova, Yu. E.; Mit'kovskaya, E. V.; Serezhkina, L. B.; Serezhkin, V. N. (2002). "Crystal Structure of Rb[UO2(SO4)F]". Radiochemistry. 44 (4): 315–318. doi:10.1023/A:1020652306275. S2CID 92322197.
  63. ^ a b c d e f Doran, Michael B.; Cockbain, Ben E.; O'Hare, Dermot (2005). "Structural variation in organically templated uranium sulfate fluorides". Dalton Transactions (10): 1774–80. doi:10.1039/b504457j. ISSN 1477-9226. PMID 15877147.
  64. ^ Olchowka, Jakub; Volkringer, Christophe; Henry, Natacha; Loiseau, Thierry (March 2014). "Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source". Journal of Fluorine Chemistry. 159: 1–7. doi:10.1016/j.jfluchem.2013.12.003.
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