Alluaudite

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Alluaudite
Alluaudite 2 Sodium iron manganese phosphate Pleasant Valley Mine near Fourmile Custer County South Dakota 2264Spp.jpg
Alluaudite
General
CategoryPhosphate minerals
Formula
(repeating unit)
(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3
IMA symbolAld[1]
Strunz classification8.AC.10
Dana classification38.2.3.6
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupC2/c
Unit cella = 11.03 Å, b = 12.53 Å
c = 6.4 Å; β = 97.57°; Z = 4
Identification
ColorDirty yellow to brownish yellow, grayish green; superficially dull greenish black, brownish black, black, when altered
Crystal habitPlaty to radiating fibrous, nodular, granular, massive
TwinningPolysynthetic
CleavageDistinct/ good on {100} and {010}, good on {110}
Mohs scale hardness5 - 5.5
StreakBrownish yellow
DiaphaneityTranslucent
Specific gravity3.4 - 3.5
Optical propertiesBiaxial (+)
Refractive indexnα = 1.782 nβ = 1.802 nγ = 1.835
Birefringenceδ = 0.053
PleochroismX = pale olive-green, straw-yellow to greenish yellow; Z = pale olive-greenish to brownish yellow
2V angleMeasured: 50° to 90°, calculated: 78°
References[2][3][4]

Alluaudite is a relatively common alkaline manganese iron phosphate mineral with formula (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3. It occurs as metasomatic replacement in granitic pegmatites and within phosphatic nodules in shales.[3]

It was first described in 1848 for an occurrence in Skellefteå, Västerbotten, Sweden. It was named by Alexis Damour after François Alluaud (II) (1778–1866).[2][3] The mineral structure was first described in 1955.[5]

References[]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b Alluaudite on Mindat.org
  3. ^ a b c Alluaudite in the Handbook of Mineralogy
  4. ^ Alluaudite data on Webmineral
  5. ^ Nowagiel M, Samsel MJ, Pietrzak TK. Towards the High Phase Purity of Nanostructured Alluaudite-Type Glass-Ceramics Cathode Materials for Sodium Ion Batteries. Materials (Basel, Switzerland). 2021 Sep;14(17). DOI: 10.3390/ma14174997. PMID: 34501086; PMCID: PMC8434363.
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