Carbonaceous sulfur hydride

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Carbonaceous sulfur hydride
Identifiers
Properties
CH8S
Molar mass 52.14 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Carbonaceous sulfur hydride is a room-temperature superconductor[1] that was announced in October 2020. The material has a maximal superconducting transition temperature of 15 °C (59 °F) at a pressure of 267 gigapascals (GPa). This is a pressure equivalent to three quarters of the pressure at the center of the Earth.[2] The material is an uncharacterized ternary polyhydride compound of carbon, sulfur and hydrogen with a chemical formula that is thought to be CSH8. Measurements under extreme pressure are difficult, and in particular the elements are too light for an X-ray determination of crystal structure (X-ray crystallography).[3] This is the closest to room temperature achieved for a superconductor, with an onset almost 30 °C higher than that of the previous record-holder.[4]

Background[]

Main article: Room-temperature superconductor

Prior to 1911, all known electrical conductors exhibited electrical resistance, due to collisions of the charge carrier with atoms in the material. Researchers discovered that in certain materials at low temperatures, the charge carriers interact with phonons in the material and form Cooper pairs, as described by BCS theory. This process results in the formation of a superconductor, with zero electrical resistance. During the transition to the superconducting state, the magnetic field lines are expelled from the interior of the material, which allows for the possibility of magnetic levitation. The effect has historically been known to occur at only low temperatures, but researchers have spent decades attempting to find a material that could operate at room temperature.[5]

Synthesis[]

The material is a ternary polyhydride compound of carbon, sulfur and hydrogen with a chemical formula that is thought to be CSH8. As of October 2020, the material's molecular structure remains uncharacterized, as extreme pressures and the light elements used are unsuitable for most measurements, such as X-ray determination.[3] The material is synthesized by compressing methane (CH4), hydrogen sulfide (H2S) and hydrogen (H2) in a diamond anvil cell and illuminating with a 532 nm green laser.[3] A starting compound of carbon and sulfur is synthesized with a 1:1 molar ratio, formed into balls less than five microns in diameter, and placed into a diamond anvil cell. Hydrogen gas is then added and the system is compressed to 4.0 GPa and illuminated with a 532-nm laser for several hours. It was reported that the crystal is not stable under 10 GPa and can be destroyed if left at room temperature overnight.[3] Research into the material is ongoing and, as of August 2020, scientists have yet to determine its molecular structure.[2]

Superconductivity[]

On 14 October 2020, it was reported that carbonaceous sulfur hydride had been confirmed as the world's first room-temperature superconductor.[2][6][7][8][9][5][10] The superconducting state was observed at temperatures as high as 15 °C (59 °F).[11][12] The material sets a new record for high-temperature superconductivity, with a transition temperature almost 30 °C (54 °F) higher than the previous record holder.[4] With a high superconducting transition of 15 °C, it is the first material known which does not have to be cooled to enter a superconducting phase.[2] Despite the enormous advancement, the superconducting state is observable only at the very high pressure of 267 GPa (38.7 million psi), which is about a million times higher than the pressure in a typical car tyre.[12]

The highest superconducting transition temperature found was 287.7 ± 1.2 K (14.6 ± 1.2 °C; 58.2 ± 2.2 °F) at a pressure of 267 ± 10 GPa (38.7 ± 1.5 million psi). The material was tested at several lower pressures, finding that at 138 ± 7 GPa (20.0 ± 1.0 million psi), the transition temperature is lowered to 147 K (−126 °C; −195 °F).[3] In addition, as expected from BCS theory, a notable decrease in the transition temperature was found when an external magnetic field is applied. The scientists found that the transition temperature was lowered by 22 K (40 °F) in a nine-tesla magnetic field at a pressure of 267 GPa.[3]

Superconductivity for sulfur hydrides without carbon was first reported in 2015[13]

The validity of these results has been called into question[14] mainly by Jorge E. Hirsch[15] as well as others[16] and also the unavailability of the data which has prompted an editor's note on the original paper.[3] The criticism focus on the measurements of AC susceptibility[17] used to test the superconductivity as the more standard Meissner effect is too hard to observe at the scale of the experiments nevertheless this effect has been measured latter on sulfur hydrides without carbon by another team[18] but those results have also been called into question.[19]

References[]

  1. ^ The technical term "room-temperature superconductor" means temperatures as low as the melting point of ice, rather than typical room temperatures.
  2. ^ a b c d Service, Robert F. (2020-10-16). "At last, room temperature superconductivity achieved". Science. 370 (6514): 273–274. Bibcode:2020Sci...370..273S. doi:10.1126/science.370.6514.273. ISSN 0036-8075. PMID 33060340. S2CID 222841128.
  3. ^ a b c d e f g Snider, Elliot; Dasenbrock-Gammon, Nathan; McBride, Raymond; Debessai, Mathew; Vindana, Hiranya; Vencatasamy, Kevin; Lawler, Keith V.; Salamat, Ashkan; Dias, Ranga P. (15 October 2020). "Room-temperature superconductivity in a carbonaceous sulfur hydride". Nature. 586 (7829): 373–377. Bibcode:2020Natur.586..373S. doi:10.1038/s41586-020-2801-z. OSTI 1673473. PMID 33057222. S2CID 222823227.
  4. ^ a b "Material sets superconducting record". Chemical & Engineering News. Retrieved 2020-10-17.
  5. ^ a b Wood, Charlie (14 October 2020). "Room-Temperature Superconductivity Achieved for the First Time". Quanta Magazine. Retrieved 2020-10-16.
  6. ^ Castelvecchi, Davide (15 October 2020). "First room-temperature superconductor excites — and baffles — scientists". Nature. 586 (7829): 349. Bibcode:2020Natur.586..349C. doi:10.1038/d41586-020-02895-0. PMID 33057238.
  7. ^ Conover, Emily (2020-10-14). "The first room-temperature superconductor has finally been found". Science News. Retrieved 2020-10-16.
  8. ^ Delbert, Caroline (2020-10-15). "In a Monumental First, Scientists Discover a Room-Temperature Superconductor". Popular Mechanics. Retrieved 2020-10-16.
  9. ^ Chang, Kenneth (2020-10-14). "Finally, the First Room-Temperature Superconductor". The New York Times. ISSN 0362-4331. Retrieved 2020-10-16.
  10. ^ Rochester, University of (2020-10-14). ""Holy Grail" Sought for More Than a Century: Researchers Synthesize Room Temperature Superconducting Material". SciTechDaily. Retrieved 2020-10-16.
  11. ^ Johnston, Hamish (14 October 2020). "Superconductivity endures to 15 °C in high-pressure material". Physics World. Retrieved 15 October 2020.
  12. ^ a b Rincon, Paul (2020-10-15). "Superconductors: Material raises hope of energy revolution". BBC News. Retrieved 2020-10-16.
  13. ^ Cartlidge, Edwin (2015). "Superconductivity record sparks wave of follow-up physics". Nature. 524 (7565): 277. Bibcode:2015Natur.524..277C. doi:10.1038/nature.2015.18191. PMID 26289188. S2CID 2294273.
  14. ^ "Breakthrough or bust? Claim of room-temperature superconductivity draws fire". Retrieved 2021-10-26.
  15. ^ Hirsch, J. E.; Marsiglio, F. (August 2021). "Unusual width of the superconducting transition in a hydride". Nature. 596 (7873): E9–E10. arXiv:2010.10307. Bibcode:2021Natur.596E...9H. doi:10.1038/s41586-021-03595-z. ISSN 1476-4687. PMID 34433940. S2CID 237306217.
  16. ^ Dogan, Mehmet; Cohen, Marvin L. (2021-04-15). "Anomalous behavior in high-pressure carbonaceous sulfur hydride". Physica C: Superconductivity and Its Applications. 583: 1353851. arXiv:2012.10771. Bibcode:2021PhyC..58353851D. doi:10.1016/j.physc.2021.1353851. ISSN 0921-4534. S2CID 229340504.
  17. ^ Hirsch, J. E. (2021-09-26). "On the ac magnetic susceptibility of a room temperature superconductor: anatomy of a probable scientific fraud". Physica C: Superconductivity and Its Applications: 1353964. arXiv:2110.12854. doi:10.1016/j.physc.2021.1353964. ISSN 0921-4534. S2CID 239194714.
  18. ^ Minkov, Vasily; Bud'ko, Sergey; Balakirev, Fedor; Prakapenka, Vitali; Chariton, Stella; Husband, Rachel; Liermann, Hanns-Peter; Eremets, Mikhail (2021-10-26). "The Meissner effect in high-temperature hydrogen-rich superconductors under high pressure". {{cite journal}}: Cite journal requires |journal= (help)
  19. ^ Hirsch, J. E.; Marsiglio, F. (2021-10-17). "Clear evidence against superconductivity in hydrides under high pressure". arXiv:2110.07568 [cond-mat.supr-con].

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