Lyonium ion

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In chemistry, a lyonium ion is the cation derived by the protonation of a solvent molecule.[1] For example, a hydronium ion is formed by the protonation of water, and CH
3
OH+
2
is the cation formed by the protonation of methanol.

Its counterpart is a lyate ion, the anion formed by the deprotonation of a solvent molecule.

Lyonium and lyate ions, resulting from molecular autoionization, contribute to the molar conductivity of protolytic solvents.

Examples[]

Lyate ion Original solvent Lyonium ion
name formula name formula name formula
Fluoride F
Hydrogen fluoride HF Fluoronium H
2
F+
Hydroxide HO
Water H
2
O
Hydronium H
3
O+
Azanide NH
2
Ammonia NH
3
Ammonium NH+
4
CH
3
Methane CH
4
Methanium CH+
5
Methoxide CH
3
O
Methanol CH
4
O
CH
5
O+

See also[]

References[]


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