Robert G. Bergman

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Robert George Bergman
BornMay 23, 1942
Alma materUniversity of Wisconsin-Madison, Ph.D. (1966)
Carleton College B.S. (1963)
AwardsWolf Prize in Chemistry (2017)
Scientific career
FieldsOrganic Chemistry, Organometallic Chemistry
ThesisReactions of Methylnorbornyl Cations and Reactions of the 3-Nortricyclyl-3-carbinyl Cation (1966)
Doctoral advisorJerome A. Berson
Other academic advisorsRonald Breslow
Doctoral studentsJohn F. Hartwig, Vy Maria Dong, Karen Goldberg, Eric Jacobsen (chemist), Patrick L. Holland, William D. Jones, Patrick J. Walsh
Other notable studentsJulie Kovacs
WebsiteLink

Robert George Bergman is an American chemist. He is Professor of the Graduate School and Gerald E. K. Branch Distinguished Professor Emeritus at the University of California, Berkeley.[1]

Early life and education[]

Born in Chicago, Robert Bergman was the son of Joseph J. and Stella Bergman, née Horowitz. In 1963 he graduated from Carleton College with a degree in chemistry. Under the supervision of Jerome A. Berson, he received a PhD in 1966 from the University of Wisconsin-Madison. From 1966 to 1967 he was a NATO postdoctoral fellow at Ronald Breslow's laboratory at Columbia University, New York City.[1]

Career[]

Bergman began his independent career at the California Institute of Technology in Pasadena where he was an Arthur Noyes Research Instructor (1967–1969), assistant professor (1969–1971), associate professor (1971–1973), and full professor (1973–1977).[2] From 1977 to 2002 he was a chemistry professor at the University of California, Berkeley and since 1978 has also been a researcher at the Lawrence Berkeley National Laboratory. In 2002 he was appointed Gerald E. K. Branch Distinguished Professor of Chemistry. Bergman transitioned to Emeritus status in 2016 and now holds to the titles of Professor of the Graduate School and Gerald E. K. Branch Distinguished Professor Emeritus.[1]

Research[]

Bergman works in the field of organic chemistry. He first investigated the reaction mechanisms of organic reactions at Caltech. He developed methods for the representation of very reactive molecules, for example 1,3-diradicals and vinyl cations. In 1972, he discovered the thermal cyclization of cis-1,5-hexadiyne-3-ene to 1,4-dehydrobenzene-diradicals, now known as the Bergman cyclization.[3][4] This reaction later played a major role in understanding the mode of action of enediyne antitumor antibiotics.[5][6] Since the mid-1970s, Bergman has also been working in the field of organometallic chemistry.[7] He contributed to the synthesis and reaction of organometallic complexes and investigated organometallic compounds with metal-oxygen and metal-nitrogen bonds. He also discovered the first soluble organometallic complexes of the transition metals, to which the addition of a saturated hydrocarbon (C-H activation, C-H insertion) succeeded.[8]

Personal life[]

Since June 17, 1965, Bergman has been married. They have two sons.

Awards and honours[]

  • 1969: Alfred P. Sloan Fellowship[9]
  • 1970: Teacher-Scholar Award (Camille and Henry Dreyfus Foundation)[9]
  • 1978: Student Government Award for Excellence in Teaching (California Institute of Technology)[9]
  • 1984: Sherman Fairchild Distinguished Scholar[9]
  • 1985: Distinguished Alumni Achievement Award (Carleton College)[9]
  • 1985: John Bailar Medal (University of Illinois)[9]
  • 1986: ACS Award in Organometallic Chemistry (American Chemical Society)[9]
  • 1987: Arthur C. Cope Scholar award (American Chemical Society)[9]
  • 1990: Edgar Fahs Smith Award (American Chemical Society)[9]
  • 1990: Ira Remsen Award (American Chemical Society)[10]
  • 1991: MERIT Award (National Institutes of Health)[9]
  • 1994: Ernest Orlando Lawrence Award (U.S. Department of Energy)[9]
  • 1995: Honorary PhD degree of Carleton College[9]
  • 1996: Arthur C. Cope Award (American Chemical Society)[9]
  • 1999: Chemical Pioneer Award (American Institute of Chemists)
  • 2001: Edward Leete Award for Teaching and Research in Organic Chemistry (American Chemical Society)
  • 2002: Teaching Award (UC Berkeley Department of Chemistry)
  • 2003: James Flack Norris Award in Physical Organic Chemistry (American Chemical Society)
  • 2003: Monie A. Ferst Award (Sigma Xi)[11]
  • 2004: Award for Excellence in Technology Transfer (Lawrence Berkeley National Laboratory)
  • 2007: NAS Award in Chemical Sciences (National Academy of Sciences)
  • 2013:
  • 2014: Technion-Israel Institute of Technology Distinguished Schulich Lectureship Award
  • 2014: Welch Award in Chemistry
  • 2014: Royal Society of Chemistry
  • 2017: Wolf Prize in Chemistry[12]

Memberships[]

Literature[]

  • Who's Who in America. 2007, ISBN 0-8379-7006-7, p. 341.

References[]

  1. ^ a b c "Robert G. Bergman | College of Chemistry". chemistry.berkeley.edu. Retrieved 2021-05-14.
  2. ^ "Robert G. Bergman – Bergman Group". Retrieved 2021-05-14.
  3. ^ Richard R. Jones, Robert G. Bergman: p-Benzyne. Generation as an intermediate in a thermal isomerization reaction and trapping evidence for the 1,4-benzenediyl structure. In: Journal of the American Chemical Society. Volume 94, Nr. 2, 1972, p. 660–661.
  4. ^ Bergman, Robert G. (1973-01-01). "Reactive 1,4-dehydroaromatics". Accounts of Chemical Research. 6 (1): 25–31. doi:10.1021/ar50061a004. ISSN 0001-4842.
  5. ^ Lee, May D.; Ellestad, George A.; Borders, Donald B. (1991-08-01). "Calicheamicins: discovery, structure, chemistry, and interaction with DNA". Accounts of Chemical Research. 24 (8): 235–243. doi:10.1021/ar00008a003. ISSN 0001-4842.
  6. ^ Nicolaou, K. C.; Dai, W.-M. (1991). "Chemistry and Biology of the Enediyne Anticancer Antibiotics". Angewandte Chemie International Edition in English. 30 (11): 1387–1416. doi:10.1002/anie.199113873. ISSN 1521-3773.
  7. ^ Chirik, Paul J. (2017-03-13). "Introduction to the Virtual Issue Honoring Robert Bergman's 2017 Wolf Prize in Chemistry". Organometallics. 36 (5): 957–959. doi:10.1021/acs.organomet.7b00134. ISSN 0276-7333.
  8. ^ A. H. Janowicz und R. G. Bergman: C-H activation in completely saturated hydrocarbons. Direct observation of M + R-H right arrow M(R)(H). In: Journal of the American Chemical Society. Volume 104, 1982, p. 352–354; almost at the same time with J. K. Hoyano und W. A. G. Graham: Oxidative addition of the carbon hydrogen-bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex. In: Journal of the American Chemical Society. Volume 104, 1982, p. 3723–3725.
  9. ^ a b c d e f g h i j k l m n "Robert G. Bergman - Chemical Sciences Division Chemical Sciences Division". commons.lbl.gov. Retrieved 2021-05-14.
  10. ^ "Ira Remsen Award". Maryland Section. 14 November 2018. Archived from the original on 14 November 2018. Retrieved 14 November 2018.
  11. ^ "Robert G. Bergman". www.sigmaxi.org. Retrieved 2021-05-14.
  12. ^ Linda Wang (2017-01-16). "Robert Bergman wins Wolf Prize in Chemistry". C&EN Global Enterprise. 95 (3): 15. doi:10.1021/cen-09503-awards01.
  13. ^ "Robert Bergman". www.nasonline.org. Retrieved 2021-05-14.

External links[]

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