Scratch hardness

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Scratch hardness tests are used to determine the hardness of a material to scratches and abrasion. The earliest test was developed by mineralogist Friedrich Mohs in 1820 (see Mohs scale). It is based on relative scratch hardness, with talc assigned a value of 1 and diamond assigned a value of 10. Mohs's scale had two limitations: it was not linear, and most modern abrasives fall between 9 and 10.

Raymond R. Ridgway, a research engineer at the Norton Company, modified the Mohs scale by giving garnet a hardness of 10 and diamond a hardness of 15.[1] Charles E. Wooddell, working at the , extended the scale further by using resistance to abrasion, and extrapolating the scale based on seven for quartz and nine for corundum, resulting in a value of 42.4 for South American brown diamond bort.[2] Resistance to abrasion is less affected by surface variations than other methods of indentations.

There is a linear relationship between cohesive energy density (lattice energy per volume) and Wooddell wear resistance, occurring between corundum (H=9) and diamond (H=42.5).[3]

Material Mohs' scale [1] [2]
talc 1 1
gypsum 2 2
calcite 3 3
fluorite 4 4
apatite 5 5
orthoclase 6 6
vitreous silica 7
quartz 7 8 7
topaz 8 9
garnet 8.92[2] 10
corundum 9 9
fused zirconia 11
fused alumina 9.03–9.065[2] 12 10
tungsten carbide 9.09[2] 12.0
silicon carbide 9.13–9.17[2] 13 14.0
boron carbide 9.32[2] 14 19.7
diamond carbonado 9.82[2] 15 36.4
ballas 9.99[2] 42.0
bort 10[2] 42.4

References[]

  1. ^ a b Ridgway, Raymond R; Ballard, Archibald H; Bailey, Bruce L. (1933). "Hardness Values for Electrochemical Products". Transactions of the Electrochemical Society. 63: 369. doi:10.1149/1.3493827.
  2. ^ a b c d e f g h i j Wooddell, Charles E. (1935). "Method of Comparing the Hardness of Electric Furnace Products and Natural Abrasives". Transactions of the Electrochemical Society. 68: 111–130. doi:10.1149/1.3493860.
  3. ^ Plendl, Johannes N.; Gielisse, Peter J. (1 Feb 1962). "Hardness of Nonmetallic Solids on an Atomic Basis". Physical Review. 125 (3): 828–832. Bibcode:1962PhRv..125..828P. doi:10.1103/PhysRev.125.828.


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