Vinyl bromide

Vinyl bromide
Names
	Preferred IUPAC name Bromoethene
	Other names Vinyl bromide; 1-Bromoethene; Bromoethylene; 1-Bromoethylene; Monobromoethene; Monobromoethylene
Identifiers
CAS Number	593-60-2 ;
3D model (JSmol)	Interactive image;
ChemSpider	11151 ;
ECHA InfoCard	100.008.911
EC Number	209-800-6;
KEGG	C19184 ;
PubChem CID	11641;
RTECS number	KU8400000;
UNII	83NRW59KFY ;
CompTox Dashboard (EPA)	DTXSID8021432 ;
	show InChI
	show SMILES
Properties
Chemical formula	C2H3Br
Molar mass	106.95 g/mol
Appearance	Colorless gas
Odor	pleasant
Density	1.525 g/cm3 at boiling point (liquid) 1.4933 g/cm3 at 20 °C
Melting point	−137.8 °C (−216.0 °F; 135.3 K)
Boiling point	15.8 °C (60.4 °F; 288.9 K)
Solubility in water	Insoluble
log P	1.57
Vapor pressure	206.8 kPa at 37.8 °C
Hazards
Main hazards	Toxic (T), Highly flammable (F+)
Safety data sheet	See: data page
R-phrases (outdated)	R12, R20/21/22, R36/37/38, R45
S-phrases (outdated)	S45, S53
NFPA 704 (fire diamond)	2 4 1
Flash point	5 °C (41 °F; 278 K)
Autoignition; temperature	530 °C (986 °F; 803 K)
Explosive limits	9%-15%
	NIOSH (US health exposure limits):
PEL (Permissible)	none
REL (Recommended)	Ca
IDLH (Immediate danger)	N.D.
Supplementary data page
Structure and; properties	Refractive index (n),; Dielectric constant (εr), etc.
Thermodynamic; data	Phase behaviour; solid–liquid–gas
Spectral data	UV, IR, NMR, MS
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	(what is ?)
	Infobox references

Vinyl bromide is a simple vinyl halide. It is a colorless liquid. It is produced from ethylene dibromide. It is mainly used as a comonomer to confer fire retardant properties to acrylate polymers.^[2]

Reactions and applications[]

It reacts with magnesium to give the corresponding Grignard reagent.^[3]

Safety precautions[]

Vinyl bromide is listed in List of IARC Group 2A carcinogens as a suspected human carcinogen.

References[]

^ Jump up to: ^a ^b ^c ^d ^e NIOSH Pocket Guide to Chemical Hazards. "#0657". National Institute for Occupational Safety and Health (NIOSH).
^ Dagani, M. J.; Barda, H. J.; Benya, T. J.; Sanders, D. C. "Bromine Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a04_405.
^ Dietmar Seyferth (1959). "Di-n-butyldivinyltin". Org. Synth. 39: 10. doi:10.15227/orgsyn.039.0010.

External links[]

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[PGCH-1] Jump up to: ^a ^b ^c ^d ^e NIOSH Pocket Guide to Chemical Hazards. "#0657". National Institute for Occupational Safety and Health (NIOSH).

[Ullmann-2] Dagani, M. J.; Barda, H. J.; Benya, T. J.; Sanders, D. C. "Bromine Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a04_405.

[3] Dietmar Seyferth (1959). "Di-n-butyldivinyltin". Org. Synth. 39: 10. doi:10.15227/orgsyn.039.0010.

[1]

[2]

[3]

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Vinyl bromide

Contents

Reactions and applications[]

Safety precautions[]

See also[]

References[]

External links[]

Names

Preferred IUPAC name Bromoethene
Other names Vinyl bromide 1-Bromoethene Bromoethylene 1-Bromoethylene Monobromoethene Monobromoethylene
Identifiers
CAS Number	593-60-2^Y
3D model (JSmol)	Interactive image
ChemSpider	11151^N
ECHA InfoCard	100.008.911
EC Number	209-800-6
KEGG	C19184^Y
PubChem CID	11641
RTECS number	KU8400000
UNII	83NRW59KFY^Y
CompTox Dashboard (EPA)	DTXSID8021432
show InChI InChI=1S/C2H3Br/c1-2-3/h2H,1H2^N Key: INLLPKCGLOXCIV-UHFFFAOYSA-N^N InChI=1/C2H3Br/c1-2-3/h2H,1H2 Key: INLLPKCGLOXCIV-UHFFFAOYAI
show SMILES C=CBr
Properties
Chemical formula	C₂H₃Br
Molar mass	106.95 g/mol
Appearance	Colorless gas
Odor	pleasant^[1]
Density	1.525 g/cm³ at boiling point (liquid) 1.4933 g/cm³ at 20 °C
Melting point	−137.8 °C (−216.0 °F; 135.3 K)
Boiling point	15.8 °C (60.4 °F; 288.9 K)
Solubility in water	Insoluble
log P	1.57
Vapor pressure	206.8 kPa at 37.8 °C
Hazards
Main hazards	Toxic (T), Highly flammable (F+)
Safety data sheet	See: data page
R-phrases (outdated)	R12, R20/21/22, R36/37/38, R45
S-phrases (outdated)	S45, S53
NFPA 704 (fire diamond)	2 4 1
Flash point	5 °C (41 °F; 278 K)
Autoignition temperature	530 °C (986 °F; 803 K)
Explosive limits	9%-15%^[1]
NIOSH (US health exposure limits):
PEL (Permissible)	none^[1]
REL (Recommended)	Ca^[1]
IDLH (Immediate danger)	N.D.^[1]
Supplementary data page
Structure and properties	Refractive index (n), Dielectric constant (ε_r), etc.
Thermodynamic data	Phase behaviour solid–liquid–gas
Spectral data	UV, IR, NMR, MS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N (what is ^YN ?)
Infobox references