(Triphenylphosphine)iron tetracarbonyl

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(Triphenylphosphine)iron tetracarbonyl
FeP(CO)4.svg
Identifiers
  • 35679-07-3
3D model (JSmol)
ChemSpider
  • InChI=1S/C18H15P.4CO.Fe/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;4*1-2;/h1-15H;;;;;
    Key: GHXDZMLBRWBQAM-UHFFFAOYSA-N
  • [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Fe]
Properties
C22H15FeO4P
Molar mass 430.177 g·mol−1
Appearance white solid
Melting point 262–266 °C (504–511 °F; 535–539 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

(Triphenylphosphine)iron tetracarbonyl is a coordination complex with the formula Fe(CO)4(PPh3) (Ph = C6H5). A off-white solid, this complex is derived from iron pentacarbonyl by replacement of one carbonyl ligand by triphenylphosphine (PPh3). The substitution is catalyzed by cobalt chloride.[1] (Triphenylphosphine)iron tetracarbonyl is an intermediate in the synthesis of bis(triphenylphosphine)iron tricarbonyl. Both the mono- and bis(triphenylphosphine) complexes were originally described by Walter Reppe.[2]

References[]

  1. ^ Albers, Michel O.; Singleton, Eric; Coville, Neil J. (1989). "Tetracarbonyliron(0) Complexes Containing Group V Donor Ligands". Inorganic Syntheses. Inorganic Syntheses. 26. pp. 59–64. doi:10.1002/9780470132579.ch12. ISBN 9780470132579.
  2. ^ Reppe, Walter; Schweckendiek, Walter Joachim (1948). "Cyclisierende Polymerisation von Acetylen. III Benzol, Benzolderivate und hydroaromatische Verbindungen". Justus Liebigs Annalen der Chemie. 560: 104–116. doi:10.1002/jlac.19485600104.
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