Ammonium oxalate

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Ammonium oxalate
Ammonium oxalate.svg
Names
IUPAC name
Diammonium ethanedioate
Other names
Diammonium oxalate
Identifiers
  • 1113-38-8 checkY
  • 6009-70-7 (monohydrate) checkY
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.012.912 Edit this at Wikidata
UNII
  • InChI=1S/C2H2O4.2H3N/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H3 checkY
    Key: VBIXEXWLHSRNKB-UHFFFAOYSA-N checkY
  • InChI=1S/C2H2O4.2H3N/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H3
  • [O-]C(=O)C([O-])=O.[NH4+].[NH4+]
Properties
C2H8N2O4
Molar mass 124.096 g·mol−1
Appearance White solid
Melting point 70 C (158 F, 343.15 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N  (what is checkY☒N ?)
Infobox references

Ammonium oxalate, C2H8N2O4 – more commonly written as (NH4)2C2O4 – is an oxalate salt with ammonium (sometimes as a monohydrate). It is a colorless (white) salt under standard conditions and is odorless and non-volatile. It is the ammonium salt of oxalic acid, and occurs in many plants and vegetables.

Vertebrate[]

It is produced in the body of vertebrates by metabolism of glyoxylic acid or ascorbic acid. It is not metabolized but excreted in the urine.[1] It is a constituent of some types of kidney stone.[2][3] It is also found in guano.

Mineralogy[]

Oxammite is a natural, mineral form of ammonium oxalate. This mineral is extremely rare.[4]

Chemistry[]

Ammonium oxalate is used as an analytical reagent and general reducing agent.[1] It and other oxalates are used as anticoagulants, to preserve blood outside the body.

Earth sciences[]

Acid ammonium oxalate (ammonium oxalate acidified to pH 3 with oxalic acid) is commonly employed in soil chemical analysis to extract iron and aluminium from poorly-crystalline minerals (such as ferrihydrite), iron(II)-bearing minerals (such as magnetite) and organic matter.[5][page needed]

References[]

  1. ^ a b National Center for Biotechnology Information. PubChem Compound Database; CID 14213 (accessed 15 November 2016).
  2. ^ The International Pharmacopoeia, p.1292, Volume 1, World Health Organization, 2006 ISBN 92-4-156301-X.
  3. ^ N G Coley, "The collateral sciences in the work of Golding Bird (1814-1854)", Medical History, iss.4, vol.13, October 1969, pp.372.
  4. ^ http://www.mindat.org
  5. ^ Rayment, George; Lyons, David (2011). Soil Chemical Methods - Australasia. CSIRO Publishing. ISBN 9780643101364.
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