Explosophore

Explosophores are functional groups in organic chemistry that give organic compounds explosive properties.

History[]

The term was first coined by Russian chemist in 1935^[1] and originally mistranslated in some articles as plosophore. Also of note is an auxoexplose concept (similar to chromophore and auxochrome concept), which is a group that modifies the explosive capability of the molecule. The term explosophore has been used more frequently after its use in books such as Organic Chemistry of Explosives by J. Agrawal and R. Hodgson (2007)'.^{[citation needed]}

Properties[]

Nitrogen-containing explosophores (groups I, II and II below) are particularly strong because in addition to providing oxygen they react to form molecular nitrogen, which is a very stable molecule, and thus the overall reaction is strongly exothermic. The gas formed also expands, causing the shock wave which is observed.

Classification[]

Pletz grouped the explosophores into eight distinct categories. ^[2][3]

I. −NO₂, −ON=O and −ONO₂[]

These represent

• the nitro group, a nitrogen atom bound to two oxygen atoms as well as an organic molecule (e.g. TNT, RDX)
• the nitrate ion, a nitrogen atom bound to three oxygen atoms, (e.g. nitroglycerin, ANFO)
• the nitrite ion, a nitrogen atom bound to two oxygen atoms^{[citation needed]}

Most commercially used explosives include the nitrate ion or the nitro group.

II. −N=N− and −N⁻=N⁺=N⁻−[]

The azo and azide groups respectively, connected to organic/inorganic compounds (e.g. AgN₃, Pb(N₃)₂, NH₄N₃)

III. −R_nNX_m[]

The halogenated nitrogen group X:halogen (for example NI₃ and NCl₃)

IV. −C=N−O−[]

The fulminate group (example HONC and Hg(ONC)₂)

V. −OClO₂ and −OClO₃[]

The chlorate and perchlorate groups respectively, connected to organics/inorganics (e.g. KClO₃, FOClO₃)

VI. −O−O− and −O₃−[]

The peroxide and ozonide groups respectively, connected to organics/inorganics (e.g. acetone peroxide, butanone peroxide)

VII. −C≡C⁻ M⁺[]

The acetylide group with its metal derivatives (e.g. Ag₂C₂, Cu₂C₂)

VIII. A metal atom connected by an unstable bond to the carbon of certain organic radicals[]

This class contains for instance organic compounds of mercury, thallium, and lead.

Other[]

Other substances have been characterised as explosophores outside of the eight classes as defined by Pletz.

References[]