Potassium iodate

Potassium iodate

Names
IUPAC name Potassium iodate
Other names Iodic acid, potassium salt
Identifiers
CAS Number	7758-05-6 Y
3D model (JSmol)	Interactive image
ChemSpider	22856 Y
ECHA InfoCard	100.028.938
EC Number	231-831-9
E number	E917 (glazing agents, ...)
PubChem CID	23665710
RTECS number	NN1350000
UNII	I139E44NHL Y
CompTox Dashboard (EPA)	DTXSID5058480
show InChI InChI=1S/HIO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Y Key: JLKDVMWYMMLWTI-UHFFFAOYSA-M Y InChI=1/HIO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Key: JLKDVMWYMMLWTI-REWHXWOFAL
show SMILES [K+].[O-]I(=O)=O
Properties
Chemical formula	KIO3
Molar mass	214.001 g/mol
Appearance	white crystalline powder
Odor	odorless
Density	3.89 g/cm3
Melting point	560 °C (1,040 °F; 833 K) (decomposes)
Solubility in water	4.74 g/100 mL (0 °C) 9.16 g/100 mL (25 °C) 32.3 g/100 mL (100 °C)
Solubility	soluble in KI solution insoluble in alcohol, liquid ammonia, nitric acid
Magnetic susceptibility (χ)	−63.1·10−6 cm3/mol
Hazards
GHS pictograms
GHS hazard statements	H272, H302, H318
GHS precautionary statements	P210, P280, P301+312+330, P305+351+338+310
NFPA 704 (fire diamond)	2 0 2 OX
Flash point	Non-flammable
Related compounds
Other anions	Potassium chlorate Potassium bromate
Other cations	Sodium iodate
Related compounds	Potassium iodide Potassium periodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YN ?)
Infobox references

Potassium iodate (KIO₃) is an ionic chemical compound consisting of K⁺ ions and IO₃⁻ ions in a 1:1 ratio.

Preparation and properties[]

Potassium iodate is an oxidizing agent and as such it can cause fires if in contact with combustible materials or reducing agents. It can be prepared by reacting a potassium-containing base such as potassium hydroxide with iodic acid, for example:

HIO₃ + KOH → KIO₃ + H₂O

It can also be prepared by adding iodine to a hot, concentrated solution of potassium hydroxide.

3 I₂ + 6 KOH → KIO₃ + 5 KI + 3 H₂O

Or by fusing potassium iodide with potassium chlorate, bromate or perchlorate, the melt is extracted with water and potassium iodate is isolated from the solution by crystallization:^[1]

KI + KClO₃ → KIO₃ + KCl

Conditions/substances to avoid include: heat, shock, friction, combustible materials, reducing materials, aluminium, organic compounds, carbon, hydrogen peroxide and sulfides.

Applications[]

Potassium iodate is sometimes used for iodination of table salt to prevent iodine deficiency. Because iodide can be oxidized to iodine by molecular oxygen under wet conditions, US companies add thiosulfates or other antioxidants to the potassium iodide. In other countries, potassium iodate is used as a source for dietary iodine. It is also an ingredient in some baby formula milk.

Like potassium bromate, potassium iodate is occasionally used as a maturing agent in baking.

Radiation protection[]

Potassium iodate may be used to protect against accumulation of radioactive iodine in the thyroid by saturating the body with a stable source of iodine prior to exposure.^[2] Approved by the World Health Organization for radiation protection, potassium iodate (KIO₃) is an alternative to potassium iodide (KI), which has poor shelf life in hot and humid climates.^[3] The UK, Singapore, United Arab Emirates, and the U.S. states Idaho and Utah are known^{[by whom?]} to stock potassium iodate in tablet form.^{[citation needed]} The government of Ireland also, following the September 11 attacks, issued potassium iodate tablets to all households.^{[4][failed verification][5]} It is not approved by the U.S. Food and Drug Administration (FDA) for use as a thyroid blocker, and the FDA has taken action against US websites that promote this use.^[6][7]

An unopened box of potassium iodate tablets, distributed to every household in Ireland in case of a terror attack on reprocessing plants such as Sellafield and nuclear power stations such as Wylfa in the United Kingdom. A scenario that upon later expert Irish examination in 2007, was found to not have justified their distribution.^[8][5] The Irish government now upon realizing their error suggests that the tablets be disposed of with municipal waste.^[5]

References[]

This article needs additional citations for verification. Please help by adding citations to reliable sources. Unsourced material may be challenged and removed. Find sources:  –  ·  ·  · scholar · JSTOR (January 2009) (Learn how and when to remove this template message)