Borate chloride
The borate chlorides are chemical compounds that contain both borate ions and chloride ions. They are mixed anion compounds. Many of them are minerals. Those minerals that crystallise with water (hydrates) may be found in evaporite deposits formed when mineral water has dried out.
List[]
chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references | |
---|---|---|---|---|---|---|---|---|---|
Na2[B(OH)4]Cl | tetragonal | P4/nmm | a = 7.25, c = 4.84 | 254.4 | 2.076 | colourless
Uniaxial (-) nω = 1.519 nε = 1.503 Max birefringence δ = 0.016 |
[1] | ||
Boracite | Mg3(B7O13)Cl | orthorhombic | Pca21 | a = 8.577, b = 8.553, c = 12.09 Z=4 | 992.5 | Biaxial (+) nα = 1.658 - 1.662 nβ = 1.662 - 1.667 nγ = 1.668 - 1.673
2V 82° Max birefringence δ = 0.010 - 0.011 |
[2] | ||
Karlite | Mg7(BO3)3(OH,Cl)5 | orthorhombic | a = 17.92, b = 17.6, c = 3.1 | 978 | 2.80 | white to light green
Biaxial (-) nα = 1.589 nβ = 1.632 nγ = 1.634 2V 24° Max birefringence δ = 0.045 |
[3] | ||
Mg5(BO3)(OH)5(Cl,OH)2 · 4H2O | monoclinic | 2.32 | colourless
Biaxial (-) nα = 1.543 nβ = 1.571 nγ = 1.577 2V 49° Max birefringence δ = 0.034 |
[4] | |||||
KNa2(Al5Mg2)[B12O18(OH)12](OH)6Cl4 · 4H2O | trigonal | R3_m | a = 15.1431, c = 14.456 Z=3 | Biaxial (-) nα = 1.535 nβ = 1.552 nγ = 1.553
2V 26° Max birefringence δ = 0.018 |
[5] | ||||
K6Al4BSi6O20(OH)4Cl | Tetragonal | a = 9.85, c = 13.06 | 1,267 | Uniaxial (+) nω = 1.525 nε = 1.525 ?
Max birefringence δ = 0.000 |
[6] | ||||
Hilgardite | Ca2[B5O9]Cl ⋅ H2O | triclinic | P1 | a=6.463 b=6.564 c=6.302 α = 61°38', β = 118°46', γ = 105°47' Z=1 | 205.8 | [7] | |||
Ca2(H3B3O7)(OH)Cl | monoclinic | a = 7.93, b = 7.26, c = 12.54 β = 94° | 720 | colourless
Biaxial (+) nα = 1.510 nβ = 1.510 nγ = 1.545 Max birefringence δ = 0.035 |
[8] | ||||
Ca2(B4O7)(Cl,OH)2 · 2H2O | hexagonal | a = 11.86, c = 23.88 | 2,909 | Uniaxial (-) nω = 1.577 nε = 1.574
Max birefringence δ = 0.003 |
[9] | ||||
Chelkarite | CaMgB2O4Cl1.5OH0.5 · 5H2O | orthorhombic | a = 13.69, b = 20.84, c = 8.26 | 2,357 | Biaxial (+) nα = 1.520 nγ = 1.558
Max birefringence δ = 0.038 |
[10] | |||
Ca3Mg(BO3)2(CO3)2.(H2O)0.36 | isometric | Fd3_m | a = 14.685 Z=4 | 3166.8 | [11] | ||||
Ca4B8O15Cl2 · 21H2O | monoclinic | a = 22.78, b = 8.74, c = 17.06 β = 96.7° | 3373 | Biaxial (+) nα = 1.499 nβ = 1.502 nγ = 1.521
2V 45° Max birefringence δ = 0.022 |
[12] | ||||
Na2Ca3B5O8(OH)2(SO4)2Cl | monoclinic | C2/c | a = 10.19, b = 7.76, c = 18.81
β = 93.33° Z=4 |
1,485 | 2.753 | Biaxial (+) nα = 1.579 nβ = 1.588 nγ = 1.604
2V 63° to 77° Max birefringence δ = 0.025 |
[13] | ||
KCa4[B5O8OH]4[B(OH)3]2Cl · 4H2O | triclinic | P1 | a = 6.57, b = 23.92, c = 6.52
α = 90.58°, β = 119.1°, γ = 95.56° |
889.2 | Biaxial (+) nα = 1.523 - 1.539 nβ = 1.539 - 1.540 nγ = 1.596 - 1.605
2V 14.6° Max birefringence δ = 0.073 |
[14] | |||
CaSr[B5O9]Cl ⋅ H2O | triclinic | P1 | a = 6.5732, b = 6.4445, c = 6.3693, α = 60.995°, β = 61.257°, γ = 77.191° Z=1 | ||||||
Chambersite | Mn2+3(B7O13)Cl | orthorhombic | Pca21 | a = 8.68, b = 8.68, c = 12.26 Z=4 | 924 | 3.49 | can be deep purple
Biaxial (+) nα = 1.732 nβ = 1.737 nγ = 1.744 2V 83° Max birefringence δ = 0.012 |
[15] | |
Fe2+3(B7O13)Cl | orthorhombic | a = 8.58, b = 8.65, c = 12.17 | 903 | Biaxial (-) nα = 1.731 nβ = 1.755 nγ = 1.755
Max birefringence δ = 0.024 |
[16] | ||||
(Fe2+,Mg)3(B7O13)Cl | trigonal | R3c | a = 8.62, c = 21.05 | 1355 | pink
Uniaxial (-) nω = 1.755 nε = 1.731 Max birefringence δ = 0.024 |
[17] | |||
(Mg,Fe)3(B7O13)Cl | trigonal | a = 8.57, c = 20.99 | 1335 | pale blue
Uniaxial (-) nω = 1.684 nε = 1.668 Max birefringence δ = 0.016 |
[18] | ||||
Cu[B(OH)4]Cl | tetragonal | P4/nmm | a = 6.19 Å, c = 5.61 Z=2 | 214.9 | deep blue
Uniaxial (-) nω = 1.691 - 1.692 nε = 1.640 - 1.641 Max birefringence δ = 0.051 |
[19] | |||
Mg3B7O13Cl | 392.05 | orthorhombic | Pca21 | a=8.5319 b=8.5282 c=12.0730 Z=4 | 878.45 | 2.964 | NLO | [20] | |
Ba6BO3Cl9 | 1201.90 | monoclinic | P21/n | a=8.229 b=12.259 c=19.080 β=90.20 Z=4 | 1924.7 | 4.418 | colourless | [21] | |
NaBa4Al2B8O18Cl3 | tetragonal | P42nm | a = 12.048, c = 6.817 | NLO | [22] | ||||
NaBa4(GaB4O9)2Cl3 | 1192.62 | tetragonal | P42nm | a=12.1033 c=6.8329 Z=2 | 1001.0 | 3.957 | SHG 1.5xKDP | [23] | |
LaCl(BO2)2 | triclinic | [24] | |||||||
CeCl(BO2)2 | triclinic | P1_ | a = 4.2174; b = 6.5763; c = 8.1221 α = 82, 152; β = 89, 206; γ = 72.048°; Z = 2 | [24] | |||||
Ce3Cl3[BO3]2 | hexagonal | P63/m | a = 9.2008, c = 5.8079; Z = 2 | [24] | |||||
PrCl(BO2)2 | triclinic | [24] | |||||||
Sm4[B16O26(OH)4(H2O)3Cl4] | [25] | ||||||||
Eu4[B16O26(OH)4(H2O)3Cl4] | [25] | ||||||||
Gd4[B16O26(OH)4(H2O)3Cl4] | [25] | ||||||||
Pb6BO4Cl7 | 1566 | triclinic | P1_ | a=8.001 b=8.054 c=13.116 α=89.52 β=89.66 γ=69.942 | 793.9 | 6.551 | colourless | [21] | |
Pu4[B16O26(OH)4(H2O)3Cl4] | [26] | ||||||||
Am4[B16O26(OH)4(H2O)3Cl4] | [26] | ||||||||
Cm4[B16O26(OH)4(H2O)3Cl4] | [26] | ||||||||
Cf4[B16O26(OH)4(H2O)3Cl4] | [26] |
References[]
- ^ "Teepleite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Boracite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Karlite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Shabynite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Satimolite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Kalborsite". www.mindat.org. Retrieved 2020-12-15.
- ^ Rumanova, I. M.; Iorysh, Z. I.; Belov, N. V. (1977). "Crystal structure of triclinic hilgardite Ca2[B5O9]Cl⋅H2O=Ca2[Bt3BΔ2O9]Cl⋅H2O". Dokl. Akad. Nauk SSSR. 23 (1): 91–94. Retrieved 2020-12-10 – via www.mathnet.ru.
- ^ "Solongoite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Ekaterinite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Chelkarite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Sakhaite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Hydrochlorborite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Heidornite". www.mindat.org. Retrieved 2020-12-15.
- ^ "Volkovskite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Chambersite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Ericaite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Congolite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Trembathite". www.mindat.org. Retrieved 2020-12-14.
- ^ "Bandylite". www.mindat.org. Retrieved 2020-12-14.
- ^ Wang, Zujian; Qiao, Huimin; Su, Rongbing; Hu, Bing; Yang, Xiaoming; He, Chao; Long, Xifa (October 2018). "Mg 3 B 7 O 13 Cl: A New Quasi-Phase Matching Crystal in the Deep-Ultraviolet Region". Advanced Functional Materials. 28 (41): 1804089. doi:10.1002/adfm.201804089.
- ^ a b Li, Wei; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2020). "Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra". Chemical Communications. 56 (45): 6086–6089. doi:10.1039/D0CC01927E. ISSN 1359-7345. PMID 32352464.
- ^ Zhang, Jianxiu; Zhang, Shufeng; Wu, Yicheng; Wang, Jiyang (2012-06-18). "New Nonlinear Optical Crystal: NaBa 4 Al 2 B 8 O 18 Cl 3". Inorganic Chemistry. 51 (12): 6682–6686. doi:10.1021/ic300306v. ISSN 0020-1669. PMID 22663174.
- ^ Wen, Ming; Su, Xin; Wu, Hongping; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2016-03-24). "NaBa 4 (GaB 4 O 9 ) 2 X 3 (X = Cl, Br) with NLO-Active GaO 4 Tetrahedral Unit: Experimental and ab Initio Studies". The Journal of Physical Chemistry C. 120 (11): 6190–6197. doi:10.1021/acs.jpcc.6b00265. ISSN 1932-7447.
- ^ a b c d Nikelski, Tanja; Schleid, Thomas (January 2003). "Zwei Cer(III)-Chlorid-Oxoborate im Vergleich: Ce3Cl3[BO3]2 und CeCl(BO2)2". Zeitschrift für anorganische und allgemeine Chemie (in German). 629 (1213): 2200–2205. doi:10.1002/zaac.200300208. ISSN 0044-2313.
- ^ a b c Stritzinger, Jared Tyler (2015). "Synthetic Exploration of F-Element Borates and Plumbites". Cite journal requires
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(help) - ^ a b c d Stritzinger, Jared Tyler (2015). "Synthetic Exploration of F-Element Borates and Plumbites". Cite journal requires
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- Borate chlorides