Mercury(II) nitrate

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Mercury(II) nitrate
Mercury nitrate.png
Names
IUPAC names
Mercury dinitrate
Mercury(II) nitrate
Other names
Mercuric nitrate
Identifiers
  • 10045-94-0 checkY
  • 7783-34-8 (monohydrate) ☒N
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.126 Edit this at Wikidata
EC Number
  • 233-152-3
RTECS number
  • OW8225000
UNII
UN number 1625
  • InChI=1S/Hg.2NO3/c;2*2-1(3)4/q+2;2*-1 ☒N
    Key: ORMNPSYMZOGSSV-UHFFFAOYSA-N ☒N
  • InChI=1/Hg.2NO3/c;2*2-1(3)4/q+2;2*-1
    Key: ORMNPSYMZOGSSV-UHFFFAOYAS
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Hg+2]
Properties
Hg(NO3)2
Molar mass 324.60 g/mol (anhydrous)
Appearance colorless crystals or white powder
Odor sharp
Density 4.3 g/cm3 (monohydrate)
Melting point 79 °C (174 °F; 352 K) (monohydrate)
soluble
Solubility soluble in nitric acid, acetone, ammonia
insoluble in alcohol
−74.0·10−6 cm3/mol
Hazards
Safety data sheet ICSC 0980
GHS labelling:
GHS03: OxidizingGHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
H272, H300, H310, H330, H373, H410
NFPA 704 (fire diamond)
3
0
1
OX
Flash point Non-flammable
Related compounds
Other anions
Mercury(II) sulfate
Mercury(II) chloride
Other cations
Zinc nitrate
Cadmium nitrate
Related compounds
Mercury(I) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N  (what is checkY☒N ?)
Infobox references

Mercury(II) nitrate is an inorganic compound with the formula Hg(NO3)2.xH2O. These colorless or white soluble crystalline salts are occasionally used as a reagent. It is made by treating mercury with hot concentrated nitric acid. Neither anhydrous nor monohydrate has been confirmed by X-ray crystallography.[1] The anhydrous material is more widely used.

Uses[]

Mercuric nitrate has been used in mercuration of ketones.[2]

Health information[]

Mercury compounds are highly toxic.

See also[]

  • The Hatter
  • Mercury poisoning
  • Gilding

References[]

  1. ^ . doi:10.1002/zaac.200500344. Cite journal requires |journal= (help); Missing or empty |title= (help)
  2. ^ Morton, Avery A.; Penner, Hellmut P. (1951). "Mercuration of Ketones and Some Other Compounds with Mercuric Nitrate". Journal of the American Chemical Society. 73 (7): 3300–3304. doi:10.1021/ja01151a091.

External links[]

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