Thallium(III) nitrate

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Thallium(III) nitrate
Formula of Thallium(III) nitrate.png
Names
IUPAC name
thallium(3+) trinitrate
Identifiers
  • 13746-98-0 checkY
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.918 Edit this at Wikidata
UNII
  • InChI=1S/3NO3.Tl/c3*2-1(3)4;/q3*-1;+3 ☒N
    Key: KLBIUKJOZFWCLW-UHFFFAOYSA-N ☒N
  • [Tl+3].O=[N+]([O-])[O-].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Tl(NO3)3
Molar mass 390.398
Appearance colorless solid
Melting point 103 °C (217 °F; 376 K)
Boiling point decomposes
decomposes
Hazards
Safety data sheet Mallinckrodt Baker
NFPA 704 (fire diamond)
4
0
0
OX
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N  (what is checkY☒N ?)
Infobox references

Thallium(III) nitrate, also known as thallic nitrate, is a thallium compound with chemical formula Tl(NO3)3.[1] It is normally found as the trihydrate. It is a colorless and highly toxic salt. It is a strong oxidizing agent useful in organic synthesis. Among its many transformations, it oxidizes methoxyl phenols to quinone acetals, alkenes to acetals, and cyclic alkenes to ring-contracted aldehydes.[2]

References[]

  1. ^ MSDS for thallium(III) nitrate[permanent dead link]
  2. ^ Mukund P. Sibi, Luiz F. Silva Jr., Vânia M. T. Carneiro "Thallium(III) Nitrate Trihydrate" Encyclopedia of Reagents for Organic Synthesis 2008 John Wiley & Sons. doi:10.1002/047084289X.rt085.pub2
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Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO
3)−
4 		RONO2 NO−
3
NH4NO3 		HOONO2 FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3 		Co(NO3)2
Co(NO3)3 		Ni(NO3)2 CuNO3
Cu(NO3)2 		Zn(NO3)2 Ga(NO3)3 Ge As Se BrNO3 Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru(NO3)3 Rh(NO3)3 Pd(NO3)2
 AgNO3
 Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb(NO3)3 Te INO3 Xe(NO3)2
CsNO3 Ba(NO3)2   Hf(NO3)4 Ta W Re Os Ir
Au(NO3)3 Hg2(NO3)2
Hg(NO3)2
Tl(NO3)3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po(NO3)4 At Rn
  Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3
Ce(NO3)4 		Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3 Lu(NO3)3
Ac(NO3)3 Th(NO3)4 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk Cf Es Fm Md No Lr
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