Tin(IV) nitrate

From Wikipedia, the free encyclopedia
Tin(IV) nitrate[1][2]
Names
Other names
  • Stannic nitrate
Identifiers
  • 13826-70-5
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.222.600 Edit this at Wikidata
EC Number
  • 694-339-7
  • InChI=1S/4NO3.Sn/c4*2-1(3)4;/q4*-1;+4
    Key: YQMWDQQWGKVOSQ-UHFFFAOYSA-N
  • [N+](=O)([O-])O[Sn](O[N+](=O)[O-])(O[N+](=O)[O-])O[N+](=O)[O-]
Properties
Molar mass 366.73 g/mol
Appearance Silky Crystals
Melting point 50 °C (122 °F; 323 K) (decomposition)
Reacts
Hazards
GHS labelling:
GHS03: Oxidizing GHS05: Corrosive
Signal word
 Danger
H272, H314
P220, P280, P305+P351+P338, P310
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Tin(IV) nitrate is a salt of tin with nitric acid. Unlike other nitrates it reacts with water to produce nitrogen dioxide. It was first prepared in the 1960s. Tin(IV) chloride was added to melted dinitrogen pentoxide which created tin(IV) nitrate and nitryl chloride.[3]

Reactions[]

Tin(IV) nitrate reacts with trifloroacetic acid anhydride to yield (NO2+)2[Sn(OOCCF3)62−] which is a nitronium salt. With trifluoroacetic acid a similar compound solvated with trifluoroacetic acid is produced.[4]

References[]

  1. ^ "Tin(IV) Nitrate". American Elements. American Elements. Retrieved 16 February 2021.
  2. ^ "Tin(IV) nitrate". Sigma-Aldrich. Sigma-Aldrich. Retrieved 16 February 2021.
  3. ^ Chemical Society (Great Britain) (1965). Journal of the Chemical Society. The Society. p. 598. Titles of chemical papers in British and foreign journals" included in Quarterly journal
  4. ^ Harrison, Philip G.; Khalil, Mutassim I.; Logan, Norman (January 1978). "A contribution to the chemistry of tin(IV) nitrate". Inorganica Chimica Acta. 30: 165–170. doi:10.1016/S0020-1693(00)89031-3.
  • v
  • t
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO
3)−
4 		RONO2 NO−
3
NH4NO3 		HOONO2 FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3 		Co(NO3)2
Co(NO3)3 		Ni(NO3)2 CuNO3
Cu(NO3)2 		Zn(NO3)2 Ga(NO3)3 Ge As Se BrNO3 Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru(NO3)3 Rh(NO3)3 Pd(NO3)2
 AgNO3
 Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb(NO3)3 Te INO3 Xe(NO3)2
CsNO3 Ba(NO3)2   Hf(NO3)4 Ta W Re Os Ir
Au(NO3)3 Hg2(NO3)2
Hg(NO3)2
Tl(NO3)3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po(NO3)4 At Rn
  Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3
Ce(NO3)4 		Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3 Lu(NO3)3
Ac(NO3)3 Th(NO3)4 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk Cf Es Fm Md No Lr
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