Thulium(III) nitrate
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Other names
Thulium trinitrate, Thulium nitrate
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Identifiers | |
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3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
Tm(NO3)3 | |
Molar mass | 354.949 |
Appearance | Dark-green crystals |
Soluble | |
Hazards | |
GHS labelling: | |
Signal word
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Warning |
H272, H315, H319, H335 | |
P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501 | |
Related compounds | |
Related compounds
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Terbium(III) nitrate, Lutetium(III) nitrate, Cerium(III) nitrate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Thulium(III) nitrate is an inorganic compound, a salt of thulium and nitric acid with the chemical formula Tm(NO3)3.[1][2][3] The compound forms dark-green crystals, readily soluble in water, also forms crystalline hydrates.
Synthesis[]
Reaction of thulium and nitric acid:[4]
- Tm + 6HNO3 → Tm(NO3)3 + 3NO2 + 3H2O
Reaction of thulium hydroxide and nitric acid:
- Tm(OH)3 + 3HNO3 → Tm(NO3)3 + 3H2O
Physical properties[]
Thulium(III) nitrate forms dark-green hygroscopic crystals.
Forms crystalline hydrates of the composition Tm(NO3)3·5H2O.[5][6]
Soluble in water and ethanol.[7]
Chemical properties[]
Both the compound and its crystalline hydrate decompose on moderate heating.
Hydrated thulium nitrate thermally decomposes to form TmONO3 and decomposes to thulium oxide upon further heating.
Applications[]
Thulium(III) nitrate hydrate is used as a reagent. Also used in optical glasses, ceramics, catalysts, electrical components, and photo-optical materials.[8]
References[]
- ^ Волков, А.И.; Жарский, И.М. (2005). Большой химический справочник (in Russian). Современная школа. p. 132. ISBN 985-6751-04-7.
- ^ Skerencak, A.; Panak, Petra J.; Hauser, W.; Neck, Volker; Klenze, R.; Lindqvist-Reis, P.; Fanghänel, Thomas (January 2009). "TRLFS study on the complexation of Cm(III) with nitrate in the temperature range from 5 to 200 °C". Radiochimica Acta. 97 (8). doi:10.1524/ract.2009.1631. Retrieved 19 August 2021.
- ^ Modolo, Giuseppe; Kluxen, Paul; Geist, Andreas (January 2010). "Demonstration of the LUCA process for the separation of americium(III) from curium(III), californium(III), and lanthanides(III) in acidic solution using a synergistic mixture of bis(chlorophenyl)dithiophosphinic acid and tris(2-ethylhexyl)phosphate". Radiochimica Acta. 98 (4). doi:10.1524/ract.2010.1708.
- ^ Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. Retrieved 19 August 2021.
- ^ "Thulium(III) nitrate pentahydrate". Sigma Aldrich. Retrieved 19 August 2021.
- ^ Elements, American. "Thulium(III) Nitrate Pentahydrate". American Elements. Retrieved 19 August 2021.
- ^ Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-95. ISBN 978-1-4822-6097-7. Retrieved 19 August 2021.
- ^ "14579 Thulium(III) nitrate hydrate, REacton®, 99.9% (REO)". Alfa Aesar. Retrieved 19 August 2021.
HNO3 | He | ||||||||||||||||
LiNO3 | Be(NO3)2 | B(NO 3)− 4 |
RONO2 | NO− 3 NH4NO3 |
HOONO2 | FNO3 | Ne | ||||||||||
NaNO3 | Mg(NO3)2 | Al(NO3)3 | Si | P | S | ClONO2 | Ar | ||||||||||
KNO3 | Ca(NO3)2 | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)2 Fe(NO3)3 |
Co(NO3)2 Co(NO3)3 |
Ni(NO3)2 | CuNO3 Cu(NO3)2 |
Zn(NO3)2 | Ga(NO3)3 | Ge | As | Se | BrNO3 | Kr |
RbNO3 | Sr(NO3)2 | Y(NO3)3 | Zr(NO3)4 | Nb | Mo | Tc | Ru(NO3)3 | Rh(NO3)3 | Pd(NO3)2 |
AgNO3 |
Cd(NO3)2 | In(NO3)3 | Sn(NO3)4 | Sb(NO3)3 | Te | INO3 | Xe(NO3)2 |
CsNO3 | Ba(NO3)2 | Hf(NO3)4 | Ta | W | Re | Os | Ir | Au(NO3)3 | Hg2(NO3)2 Hg(NO3)2 |
Tl(NO3)3 |
Pb(NO3)2 | Bi(NO3)3 BiO(NO3) |
Po(NO3)4 | At | Rn | ||
Ra(NO3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | ||
↓ | |||||||||||||||||
La(NO3)3 | Ce(NO3)3 Ce(NO3)4 |
Pr(NO3)3 | Nd(NO3)3 | Pm(NO3)3 | Sm(NO3)3 | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy(NO3)3 | Ho(NO3)3 | Er(NO3)3 | Tm(NO3)3 | Yb(NO3)3 | Lu(NO3)3 | |||
Ac(NO3)3 | Th(NO3)4 | UO2(NO3)2 | Np(NO3)4 | Pu(NO3)4 | Am(NO3)3 | Cm(NO3)3 | Bk(NO3)3 | Cf | Es | Fm | Md | No | Lr |
- Thulium compounds
- Nitrates