Iodate fluoride

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The iodate fluorides are chemical compounds which contain both iodate and fluoride anions (IO3− and F−). In these compounds fluorine is not bound to iodine as it is in .

List[]

name formula weight system space group unit cell volume density properties ref
zinc iodate fluoride ZnIO3F 259.27 monoclinic P21/n a=5.030 b=5.227 c=12.471 β=96.00 Z=4 326.13 5.281 band gap 4.2 eV [1]
LiGaF2(IO3)2 464.46 monoclinic P21/n a=9.9994 b=5.1160 c=12.6619 β=106.444 Z=4 621.25 4.966 stable to 400 °C band gap 4.33 eV [2]
yttrium diiodate fluoride Y(IO3)2F 457.71 hexagonal P63 a=6.8455 c=21.807 Z=6 885.0 5.153 white [3]
Cd3(IO3)(IO4)F2·0.1CdO R3m a =15.286 c=9.574 SHG 3.0xKDP band gap 4.0 eV [4]
tin difluoride diiodate Sn(IO3)2F2 506.49 monoclinic P21 a=5.436 b=9.91 c=6.28 β=105.44 Z=2 326.3 5.155 band gap 4.08 SHG 3x; white [5]
CsVO2F(IO3) 409.75 orthorhombic Pna21 a=7.8974 b=10.2644 c=7.3854 Z=4 598.68 4.546 alkaline metals [6]
Barium iodate fluoride Ba(IO3)F 331.24 monoclinic P21/c a=10.5729 b=6.3354 c=6.0450 β=90.497° 404.90 5.434 band gap 4.32 eV; high birefringence [7]
α-Ba[VFO2(IO3)2] 589.08 Orthorhombic Pbcn a=5.1494 b=12.644 c=12.400 Z=4 807.4 4.846 colourless [8]
β-Ba[VFO2(IO3)2] 589.08 Orthorhombic P212121 a=7.1902 b=8.1964 c=13.0420 Z=4 768.6 5.091 colourless [8]
α-Ba2[VO2F2(IO3)2]IO3 920.32 Orthorhombic Pna21 a =13.578 b=11.425 c=7.500 Z=4 1163.5 5.254 colourless [8]
β-Ba2[VO2F2(IO3)2]IO3 920.32 monoclinic P21 a=7.3895 b=7.4994 c=10.9095 β=105.461 Z=2 582.69 5.245 colourless [8]
α-Ba2[GaF4(IO3)2](IO3) 945.10 orthorhombic Pna21 a=13.6984 b=11.3696 c=7.4245 Z=4 1156.76 5.429 colourless SHG 6×KDP band gap 4.61eV [9]
β-Ba2[GaF4(IO3)2](IO3) 945.10 monoclinic P21 a=7.4631 b=7.4511 c=10.9597 β=106.138 Z=2 585.24 5.361 colourless SHG 6×KDP band gap 4.35 [9]
Ce(IO3)2F2·H2O 545.94 orthorhombic Ima2 a=7.702 b=12.277 c=7.947 Z=4 751.4 4.826 light yellow [10]
K5(W3O9F4)(IO3) 1141.95 monoclinic Pm a=9.7129 b=3.7122 c=10.9575 β=102.007 Z=1 386.44 4.907 SHG 11×KDP [11]
Bi(IO3)F2 421.88 monoclinic C2 a=12.827 b=5.3089 c=6.0790 β=101.384 Z=4 405.89 6.904 SHG 11.5×KDP [12]
Bi3OF3(IO3)4 1399.54 hexagonal P63mc a=10.880 c=6.993 716.8 6.484 colourless SHG [13]
NH4Bi2(IO3)2F5 880.80 monoclinic P21 a=5.718 b=5.892 c=15.18 β=100.38 Z=2 502.9 5.817 SHG 9.2×KDP
KBi2(IO3)2F5 901.86 monoclinic P21 a=5.687 b=5.864 c=14.82 β=100.095 Z=2 486.5 6.157 colourless SHG [14]
RbBi2(IO3)2F5 948.23 monoclinic P21 a=5.7357 b=5.9095 c=15.177 β=100.263 Z=2 506.2 6.221 colourless SHG [14]
CsBi2(IO3)2F5 995.67 monoclinic P21 a=5.750 b=5.924 c=15.640 β=100.509 Z=2 523.8 6.313 colourless SHG [14]

References[]

  1. ^ Gai, Minqiang; Wang, Ying; Tong, Tinghao; Yang, Zhihua; Pan, Shilie (2020-04-06). "ZnIO 3 F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap". Inorganic Chemistry. 59 (7): 4172–4175. doi:10.1021/acs.inorgchem.0c00284. ISSN 0020-1669. PMID 32191441.
  2. ^ Chen, Jin; Hu, Chun-Li; Mao, Jiang-Gao (2021-02-01). "LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap". Science China Materials. 64 (2): 400–407. doi:10.1007/s40843-020-1395-x. ISSN 2199-4501. S2CID 220721811.
  3. ^ Peng, Guang; Yang, Yi; Yan, Tao; Zhao, Dan; Li, Bingxuan; Zhang, Ge; Lin, Zheshuai; Ye, Ning (2020). "Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional material". Chemical Science. 11 (28): 7396–7400. doi:10.1039/D0SC02789H. ISSN 2041-6520. PMC 7553043. PMID 33133489.
  4. ^ Cao, Liling; Zhang, Shengzi; Zhao, Dan; Li, Bingxuan; Yan, Tao; Yang, Guangsai; Lin, Zheshuai; Luo, Min; Ye, Ning (2021-04-06). "Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups". Inorganic Chemistry. 60 (8): 6040–6046. doi:10.1021/acs.inorgchem.1c00506. ISSN 0020-1669. PMID 33822589.
  5. ^ Luo, Min; Liang, Fei; Hao, Xia; Lin, Donghong; Li, Bingxuan; Lin, Zheshuai; Ye, Ning (2020-03-24). "Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO 3 ) 2 F 2". Chemistry of Materials. 32 (6): 2615–2620. doi:10.1021/acs.chemmater.0c00196. ISSN 0897-4756.
  6. ^ Chen, Jin; Hu, Chun‐Li; Zhang, Xiao‐Han; Li, Bing‐Xuan; Yang, Bing‐Ping; Mao, Jiang‐Gao (2020-03-23). "CsVO 2 F(IO 3 ): An Excellent SHG Material Featuring an Unprecedented 3D [VO 2 F(IO 3 )] − Anionic Framework". Angewandte Chemie International Edition. 59 (13): 5381–5384. doi:10.1002/anie.202000587. ISSN 1433-7851. PMID 32027081.
  7. ^ Fan, Huixin; Peng, Guang; Lin, Chensheng; Chen, Kaichuang; Yang, Shunda; Ye, Ning (13 May 2020). "Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence". Inorganic Chemistry. 59 (11): 7376–7379. doi:10.1021/acs.inorgchem.0c00945. PMID 32401023.
  8. ^ a b c d Yu, Hongwei; Nisbet, Matthew L.; Poeppelmeier, Kenneth R. (2018-07-18). "Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions". Journal of the American Chemical Society. 140 (28): 8868–8876. doi:10.1021/jacs.8b04762. ISSN 0002-7863. PMID 29893564.
  9. ^ a b Chen, Jin; Hu, Chun-Li; Mao, Fei-Fei; Feng, Jiang-He; Mao, Jiang-Gao (2019-02-11). "A Facile Route to Nonlinear Optical Materials: Three-Site Aliovalent Substitution Involving One Cation and Two Anions". Angewandte Chemie. 131 (7): 2120–2124. doi:10.1002/ange.201813968. PMID 30589189.
  10. ^ Abudouwufu, Tushagu; Zhang, Min; Cheng, Shichao; Yang, Zhihua; Pan, Shilie (2019-01-24). "Ce(IO 3 ) 2 F 2 ⋅H 2 O: The First Rare-Earth-Metal Iodate Fluoride with Large Second Harmonic Generation Response". Chemistry – A European Journal. 25 (5): 1221–1226. doi:10.1002/chem.201804995. PMID 30408250.
  11. ^ Wu, Chao; Lin, Lin; Jiang, Xingxing; Lin, Zheshuai; Huang, Zhipeng; Humphrey, Mark G.; Halasyamani, P. Shiv; Zhang, Chi (2019-12-24). "K 5 (W 3 O 9 F 4 )(IO 3 ): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold". Chemistry of Materials. 31 (24): 10100–10108. doi:10.1021/acs.chemmater.9b03214. hdl:1885/215315. ISSN 0897-4756.
  12. ^ Mao, Fei-Fei; Hu, Chun-Li; Xu, Xiang; Yan, Dong; Yang, Bing-Ping; Mao, Jiang-Gao (2017-02-13). "Bi(IO 3 )F 2 : The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect". Angewandte Chemie. 129 (8): 2183–2187. doi:10.1002/ange.201611770.
  13. ^ Zhang, Min; Su, Xin; Mutailipu, Miriding; Yang, Zhihua; Pan, Shilie (2017-02-14). "Bi 3 OF 3 (IO 3 ) 4 : Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response". Chemistry of Materials. 29 (3): 945–949. doi:10.1021/acs.chemmater.6b05468. ISSN 0897-4756.
  14. ^ a b c Liu, Hongming; Wu, Qi; Jiang, Xingxing; Lin, Zheshuai; Meng, Xianggao; Chen, Xingguo; Qin, Jingui (2017-08-01). "ABi 2 (IO 3 ) 2 F 5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second-Harmonic Generation Response with a Wide Bandgap". Angewandte Chemie International Edition. 56 (32): 9492–9496. doi:10.1002/anie.201705672. PMID 28631860.
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