Bromine monofluoride

Bromine monofluoride
Names
	IUPAC name Bromine monofluoride
Identifiers
CAS Number	13863-59-7;
3D model (JSmol)	Interactive image;
ChemSpider	20474212;
PubChem CID	139632;
UN number	1745
CompTox Dashboard (EPA)	DTXSID60160735 ;
	InChI InChI=1S/BrF/c1-2 Key: MZJUGRUTVANEDW-UHFFFAOYSA-N;
	SMILES FBr;
Properties
Chemical formula	BrF
Molar mass	98.903 g/mol
Density	4.403 g/L
Melting point	−33 °C (−27 °F; 240 K)
Boiling point	20 °C (68 °F; 293 K) (decomposes)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Bromine monofluoride is a quite unstable interhalogen compound with the chemical formula BrF. It can be produced through the reaction of bromine trifluoride (or bromine pentafluoride) and bromine. Due to its lability, the compound can be detected but not isolated:^[2]

BrF₃ + Br₂ → 3 BrF

BrF₅ + 2 Br₂ → 5 BrF

Br_2(l) + F_2(g) → 2 BrF_(g)

It is usually generated in the presence of cesium fluoride.^[3]

Bromine monofluoride decomposes at normal temperature through dismutation to bromine trifluoride, bromine pentafluoride, and free bromine.

References[]

^ ^a ^b ^c David R. Lide: CRC Handbook of Chemistry and Physics. 89. Auflage, Taylor & Francis, 2008, ISBN 978-1-4200-6679-1, S. 4–53.
^ Macintyre, J. E.; Daniel, F. M.; Stirling, V. M. (1992). Dictionary of Inorganic Compounds. CRC Press. p. 285. ISBN 978-0-412-30120-9.
^ Winter, Rolf; Terjeson, Robin J.; Gard, Gary L. (1998). "An Improved and Facile Preparation of SF₅Br". Journal of Fluorine Chemistry. 89: 105–106. doi:10.1016/S0022-1139(98)00094-3.

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[crc-1] David R. Lide: CRC Handbook of Chemistry and Physics. 89. Auflage, Taylor & Francis, 2008, ISBN 978-1-4200-6679-1, S. 4–53.

[2] Macintyre, J. E.; Daniel, F. M.; Stirling, V. M. (1992). Dictionary of Inorganic Compounds. CRC Press. p. 285. ISBN 978-0-412-30120-9.

[3] Winter, Rolf; Terjeson, Robin J.; Gard, Gary L. (1998). "An Improved and Facile Preparation of SF₅Br". Journal of Fluorine Chemistry. 89: 105–106. doi:10.1016/S0022-1139(98)00094-3.

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[2]

[3]

Bromine monofluoride

See also[]

References[]